| Literature DB >> 31962502 |
Eleonora Guarini1, Martin Neumann2, Stefano Bellissima3, Daniele Colognesi3, Ubaldo Bafile3.
Abstract
We present an exponential mode analysis of the dynamical processes determining the time behavior of the Kubo velocity autocorrelation function (KVAF) of fluid para-H_{2}, as obtained by ring polymer molecular dynamics simulations at various fluid densities. The mechanisms contributing to the decay of the KVAF are thoroughly characterized at a slightly supercritical temperature, in a density interval ranging from the critical point to the fluid-solid transition. We show that the quantum nature of the system does not influence the specific phenomena and decay channels through which a loss in velocity correlation takes place, since these are the same as found in classical fluids. Similarly, a dynamical crossover is observed with increasing density, signaling the onset of a transverse-like dynamics like in classical systems. We also investigate the effect of density on the processes contributing to the most relevant property of a quantum fluid, namely, the large values of the total and zero-point kinetic energy arising through the Heisenberg uncertainty principle.Year: 2019 PMID: 31962502 DOI: 10.1103/PhysRevE.100.062111
Source DB: PubMed Journal: Phys Rev E ISSN: 2470-0045 Impact factor: 2.529