Literature DB >> 31961517

Bis(Nitroxymethylisoxazolyl) Furoxan: A Promising Standalone Melt-Castable Explosive.

Eric C Johnson1, Jesse J Sabatini1, David E Chavez2, Lucille A Wells2, Joseph E Banning1, Rosario C Sausa3, Edward F C Byrd3, Joshua A Orlicki4.   

Abstract

The synthesis and crystal structure of the heterocyclic explosive bis(nitroxymethylisoxazolyl) furoxan, C10 H6 N6 O10 , are described. In addition, we report its physical properties and theoretical performance. This material was found to exhibit standalone melt-castable explosive properties, with a melting point of 89.8 °C and an onset decomposition temperature of 193.8 °C. Bis(nitroxymethylisoxazolyl) furoxan features an insensitive behavior to impact, friction, and electrostatic discharge, with a calculated detonation pressure about 25 % higher than the state-of-the-art melt-castable explosive TNT.
© 2020 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Entities:  

Keywords:  cycloaddition reactions; energetic materials; explosives; furoxans; heterocycles

Year:  2020        PMID： 31961517     DOI： 10.1002/cplu.201900710

Source DB:  PubMed          Journal:  Chempluschem        ISSN： 2192-6506            Impact factor:   2.863


  5 in total

Review 1.  A Short Review of Nitric Esters and Their Role in Energetic Materials.

Authors:  Jesse J Sabatini; Eric C Johnson
Journal:  ACS Omega       Date:  2021-04-27

2.  Nitro-, Cyano-, and Methylfuroxans, and Their Bis-Derivatives: From Green Primary to Melt-Cast Explosives.

Authors:  Alexander A Larin; Dmitry M Bystrov; Leonid L Fershtat; Alexey A Konnov; Nina N Makhova; Konstantin A Monogarov; Dmitry B Meerov; Igor N Melnikov; Alla N Pivkina; Vitaly G Kiselev; Nikita V Muravyev
Journal:  Molecules       Date:  2020-12-10       Impact factor: 4.411

3.  5-Nitrotetrazol and 1,2,4-Oxadiazole Methylene-Bridged Energetic Compounds: Synthesis, Crystal Structures and Performances.

Authors:  Jiarong Zhang; Fuqiang Bi; Zhi Yang; Qi Xue; Bozhou Wang
Journal:  Molecules       Date:  2021-11-23       Impact factor: 4.411

Review 4.  Synthetic Strategies Toward Nitrogen-Rich Energetic Compounds Via the Reaction Characteristics of Cyanofurazan/Furoxan.

Authors:  Luoluo Wang; Lianjie Zhai; Weiqing She; Minchang Wang; Junlin Zhang; Bozhou Wang
Journal:  Front Chem       Date:  2022-03-17       Impact factor: 5.221

5.  1-(Azidomethyl)-5H-Tetrazole: A Powerful New Ligand for Highly Energetic Coordination Compounds.

Authors:  Moritz Kofen; Marcus Lommel; Maximilian H H Wurzenberger; Thomas M Klapötke; Jörg Stierstorfer
Journal:  Chemistry       Date:  2022-05-25       Impact factor: 5.020
  5 in total

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