Assessment of C-DBP and N-DBP formation potential and its reduction by MIEX® DOC and MIEX® GOLD resins using fluorescence spectroscopy and parallel factor analysis.

This study investigated the applicability of parallel factor analysis (PARAFAC) of fluorescence excitation-emission matrices (EEM) spectra to assess the formation potentials (FP) of carbonaceous and nitrogenous disinfection byproducts (C-DBP and N-DBP) and the FP reduction by the magnetic ion exchange resins, MIEX® DOC and MIEX® GOLD. Two source waters of different nature - a surface water and a secondary treated wastewater effluent - were studied. The samples were analyzed for formation potentials of trihalomethanes (THM4), haloacetonitriles (HAN4), haloketones (HK2), and chloropicrin (CPN). A 4-component PARAFAC model was developed from 150 EEM samples generated from the raw source waters and their treatment with MIEX® resins. Components C1, C2, and C3 corresponded to humic-like dissolved organic matter (DOM) while C4 corresponded to protein-like DOM. Both MIEX® resins preferentially removed components C1, C2, and C3 over C4, indicating affinity with humic materials. MIEX® resins were shown to be more effective to treat surface water than secondary effluent, including effective removal of DBP precursors with extended bed volume treatment. Among all parameters investigated, THM4-FP strongly correlated with humic-like component C3, while HAN4-FP strongly correlated with protein-like component C4 (ρ > 0.89 and p < 0.01); CPN-FP and HK2-FP both correlated with anthropogenic DOM C2 (ρ > 0.89 and p < 0.01). Our results indicate that EEM-PARAFAC was valuable for assessing DBP formation potentials and removal of their precursors by MIEX® resins in different water sources.