Mixed Metal-Organic Framework with Multiple Binding Sites for Efficient C2 H2 /CO2 Separation.

The separation of C2 H2 /CO2 is particularly challenging owing to their similarities in physical properties and molecular sizes. Reported here is a mixed metal-organic framework (M'MOF), [Fe(pyz)Ni(CN)4 ] (FeNi-M'MOF, pyz=pyrazine), with multiple functional sites and compact one-dimensional channels of about 4.0 Å for C2 H2 /CO2 separation. This MOF shows not only a remarkable volumetric C2 H2 uptake of 133 cm3  cm-3 , but also an excellent C2 H2 /CO2 selectivity of 24 under ambient conditions, resulting in the second highest C2 H2 -capture amount of 4.54 mol L-1 , thus outperforming most previous benchmark materials. The separation performance of this material is driven by π-π stacking and multiple intermolecular interactions between C2 H2 molecules and the binding sites of FeNi-M'MOF. This material can be facilely synthesized at room temperature and is water stable, highlighting FeNi-M'MOF as a promising material for C2 H2 /CO2 separation.