Literature DB >> 31939207

Bis(1,2,4-oxadiazolyl) Furoxan: A Promising Melt-Castable Eutectic Material of Low Sensitivity.

Eric C Johnson1, Eric J Bukowski1, Jesse J Sabatini1, Rosario C Sausa2, Edward F C Byrd2, Melissa A Garner3, David E Chavez4.   

Abstract

A scalable synthesis of bis(1,2,4-oxadiazoyl) furoxan, C6 H2 N6 O4 , its physical properties, and its theoretical performance values are described. Previous attempts to synthesize this compound required expensive reagents, and/or time-consuming synthesis processes and low overall yields. In addition to disclosing a streamlined synthesis of bis(1,2,4-oxadiazolyl) furoxan, we report its molecular configuration and crystal structure, as well as its correct melting point. Bis(1,2,4-oxadiazolyl) furoxan exhibits a very insensitive behavior to impact, friction, and electrostatic discharge, with a calculated detonation pressure 20 % higher than that of TNT. Given its physical properties and theoretical performance values, this material can be classified as a promising ingredient in the development of melt-castable eutectic technology.
© 2019 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Entities:  

Keywords:  energetic materials; eutectic technology; explosives; heterocycles; organic synthesis

Year:  2019        PMID: 31939207     DOI: 10.1002/cplu.201800563

Source DB:  PubMed          Journal:  Chempluschem        ISSN: 2192-6506            Impact factor:   2.863


  1 in total

1.  5-Nitrotetrazol and 1,2,4-Oxadiazole Methylene-Bridged Energetic Compounds: Synthesis, Crystal Structures and Performances.

Authors:  Jiarong Zhang; Fuqiang Bi; Zhi Yang; Qi Xue; Bozhou Wang
Journal:  Molecules       Date:  2021-11-23       Impact factor: 4.411

  1 in total

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