| Literature DB >> 31939207 |
Eric C Johnson1, Eric J Bukowski1, Jesse J Sabatini1, Rosario C Sausa2, Edward F C Byrd2, Melissa A Garner3, David E Chavez4.
Abstract
A scalable synthesis of bis(1,2,4-oxadiazoyl) furoxan, C6 H2 N6 O4 , its physical properties, and its theoretical performance values are described. Previous attempts to synthesize this compound required expensive reagents, and/or time-consuming synthesis processes and low overall yields. In addition to disclosing a streamlined synthesis of bis(1,2,4-oxadiazolyl) furoxan, we report its molecular configuration and crystal structure, as well as its correct melting point. Bis(1,2,4-oxadiazolyl) furoxan exhibits a very insensitive behavior to impact, friction, and electrostatic discharge, with a calculated detonation pressure 20 % higher than that of TNT. Given its physical properties and theoretical performance values, this material can be classified as a promising ingredient in the development of melt-castable eutectic technology.Entities:
Keywords: energetic materials; eutectic technology; explosives; heterocycles; organic synthesis
Year: 2019 PMID: 31939207 DOI: 10.1002/cplu.201800563
Source DB: PubMed Journal: Chempluschem ISSN: 2192-6506 Impact factor: 2.863