Study on reaction mechanism of superior bamboo biochar catalyst production by molten alkali carbonates pyrolysis and its application for cellulose hydrolysis.

Biochar has attracted wide interest due to its important role in the synthesis of functionalized carbon materials. Molten alkali carbonates (MC) pyrolysis as a novel mean was explored to obtain superior bamboo biochar compared with alkali impregnation pretreating bamboo powder associated with pyrolysis. The properties of biochar produced by MC pyrolysis were enhanced, suggesting an increase in BET surface area of 43.59 m2/g compared with non-pretreat biochar of 5.76 m2/g, and possessed preferable pore structure than the alkali impregnation one of 39.82 m2/g and 16.98 nm for catalyst support. Besides, pyrolysis temperature reinforced the porosity and the degree of carbonization as it rising, however, the optimized temperature for top-grade biochar materials was 450 °C. The MC weakened the hydrogen bonds network in bamboo powder acting a similar role just as alkaline pretreated, meanwhile neutralized the acid produced during pyrolysis process supported by the analysis of FTIR and TGA. The potential pathways of biomass pyrolysis with MC had also been proposed. In addition, the biochar obtained was utilized as a catalyst support of biochar-bearing sulfonic acid groups, which achieved the remarkable yields of TRS and glucose (52.8% and 43.5%) in hydrolysis of cellulose.