Novel Simultaneous Removal Technology of NO and SO2 Using a Semi-Dry Microwave Activation Persulfate System.

As it has a simple system and a small floor area, flue gas simultaneous desulfurization and denitrification technology has a good development prospect, and related research has become a hot topic in the field of flue gas purification. In this work, a novel simultaneous removal technology of NO and SO2 from flue gas using a semi-dry microwave activation persulfate system was developed for the first time. A series of experiments and characterization analyses had been implemented to research the feasibility of this new flue gas purification technology. The oxidation products, free radicals, and mechanism of NO and SO2 simultaneous removal were revealed. The effect of the main technological parameters on NO and SO2 simultaneous removal was also studied. Relevant results demonstrated that an increase in the microwave radiation power, persulfate concentration, and O2 concentration enhanced NO and SO2 simultaneous removal. The increase of NO and SO2 concentrations weakened NO and SO2 simultaneous removal. The reagent dosage, pH value of the solution, and reaction temperature showed a dual influence on NO and SO2 simultaneous removal. Free-radical capture experiments revealed that both SO4-• and •OH that were produced by microwave activation of persulfate were the major active species and played very key roles in NO and SO2 simultaneous removal. The main products (sulfate and nitrate) and byproducts (NO2) in the tail gas were found. The process application and product post-treatment routes were also proposed. The result may provide the necessary inspiration and guidance for the development and application of microwave-activated advanced oxidation technology in the flue gas treatment area.