Literature DB >> 31894765

Water-soluble titanium-polyoxomolybdate with external μ3 bridging oxygen coordination on a lacunary Keggin structure.

Ming Xu1, Ting Wang, Fengyan Li, Wenjuan Xu, Yue Zheng, Lin Xu.   

Abstract

A titanium-polyoxomolybdate K6(H3O)8[{PMo9O34TiO}2]·32H2O (1) was successfully synthesized and structurally characterized. It is an unprecedented instance that the titanium-containing polyoxomolybdate is water-soluble and was synthesized by using a conventional aqueous solution method. The Ti4+ ions exist in an unusual coordination mode. Besides, compound 1 as a wide band gap semiconductor showed evident photocatalytic activity for the oxidation of benzaldehyde into benzoic acid.

Entities:  

Year:  2020        PMID: 31894765     DOI: 10.1039/c9cc07767g

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  1 in total

1.  A "concentration-induced self-assembly" strategy for Ag x H3-x PMo12O40 nanorods: synthesis, photoelectric properties and photocatalytic applications.

Authors:  Xinxin Wang; Yuting Song; Fengyan Li; Wenjuan Xu; Yue Zheng; Lin Xu
Journal:  Nanoscale Adv       Date:  2020-11-26
  1 in total

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