Literature DB >> 31880934

Photocatalytic Isocyanide-Based Multicomponent Domino Cascade toward the Stereoselective Formation of Iminofurans.

Sveva Pelliccia1, Antonella Ilenia Alfano1, Paolo Luciano1, Ettore Novellino1, Alberto Massarotti2, Gian Cesare Tron2, Davide Ravelli3, Mariateresa Giustiniano1.   

Abstract

A visible-light-promoted three-component isocyanide-based synthesis of iminofurans is herein reported. The reaction proved to be general in scope and proceeds through a triple domino process. Control experiments with 18O-labeled water and TEMPO provided key mechanistic insights for delineating the reactivity paradigms crucial to design efficient photoredox isocyanide-based domino transformations.

Entities:  

Year:  2020        PMID： 31880934     DOI： 10.1021/acs.joc.9b02709

Source DB:  PubMed          Journal:  J Org Chem        ISSN： 0022-3263            Impact factor:   4.354


  2 in total

1.  Visible-Light Photocatalytic Functionalization of Isocyanides for the Synthesis of Secondary Amides and Ketene Aminals.

Authors:  Rolando Cannalire; Jussara Amato; Vincenzo Summa; Ettore Novellino; Gian Cesare Tron; Mariateresa Giustiniano
Journal:  J Org Chem       Date:  2020-10-19       Impact factor: 4.354

2.  The Dark Side of Isocyanides: Visible-Light Photocatalytic Activity in the Oxidative Functionalization of C(sp3)-H Bonds.

Authors:  Camilla Russo; Jussara Amato; Gian Cesare Tron; Mariateresa Giustiniano
Journal:  J Org Chem       Date:  2021-12-01       Impact factor: 4.354
  2 in total

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