Literature DB >> 31873024

Methanesulfinylation of Benzyl Halides with Dimethyl Sulfoxide.

Duo Fu1, Jun Dong1, Hongguang Du1, Jiaxi Xu1.   

Abstract

A phenyltrimethylammonium tribromide-mediated nucleophilic substitution/oxygen transformation reaction of benzyl halides with DMSO has been developed. In this transition-metal-free reaction, DMSO acts as not only a solvent but also a "S(O)Me" source, thus providing a convenient method for the efficient and direct synthesis of various benzyl methyl sulfoxides.

Entities:  

Year:  2020        PMID: 31873024     DOI: 10.1021/acs.joc.9b03041

Source DB:  PubMed          Journal:  J Org Chem        ISSN: 0022-3263            Impact factor:   4.354


  1 in total

1.  Direct oxidation of N-ynylsulfonamides into N-sulfonyloxoacetamides with DMSO as a nucleophilic oxidant.

Authors:  Jun Dong; Duo Fu; Dongning Sheng; Jiayi Wang; Jiaxi Xu
Journal:  RSC Adv       Date:  2021-12-20       Impact factor: 4.036

  1 in total

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