Corn stover valorization by one-step formic acid fractionation and formylation for 5-hydroxymethylfurfural and high guaiacyl lignin production.

One-step fractionation with concentrated formic acid at elevated temperatures with short retention time was investigated for corn stover valorization. Crude pulp (CP) with high purity of cellulose and FA-lignin (FAL) with high guaiacyl content were fractionated through one-step mild pretreatment. Formylation reaction on both CP and FAL fractions occurred during the pretreatment and improved the hydrophobicity and thermal stability of CPs and FALs. The presence of formyl group on CPs significantly inhibited the enzymatic hydrolysis efficiency for sugar production, however, the formylated cellulose showed super high reactivity and selectivity for HMF production through catalysis by maleic acid and aluminum chloride in acetonitrile-water co-solvent system. In addition, the fractionated FAL fraction exhibited a loose structure which is prominent for its further catalytic conversion into chemicals and energy.