| Literature DB >> 31848248 |
Alireza Shahsafi1, Patrick Roney1, You Zhou2, Zhen Zhang3, Yuzhe Xiao1, Chenghao Wan1,4, Raymond Wambold1, Jad Salman1, Zhaoning Yu1,5, Jiarui Li6, Jerzy T Sadowski7, Riccardo Comin6, Shriram Ramanathan3, Mikhail A Kats8,4,5.
Abstract
Thermal emission is the process by which all objects at nonzero temperatures emit light and is well described by the Planck, Kirchhoff, and Stefan-Boltzmann laws. For most solids, the thermally emitted power increases monotonically with temperature in a one-to-one relationship that enables applications such as infrared imaging and noncontact thermometry. Here, we demonstrated ultrathin thermal emitters that violate this one-to-one relationship via the use of samarium nickel oxide (SmNiO3), a strongly correlated quantum material that undergoes a fully reversible, temperature-driven solid-state phase transition. The smooth and hysteresis-free nature of this unique insulator-to-metal phase transition enabled us to engineer the temperature dependence of emissivity to precisely cancel out the intrinsic blackbody profile described by the Stefan-Boltzmann law, for both heating and cooling. Our design results in temperature-independent thermally emitted power within the long-wave atmospheric transparency window (wavelengths of 8 to 14 µm), across a broad temperature range of ∼30 °C, centered around ∼120 °C. The ability to decouple temperature and thermal emission opens a gateway for controlling the visibility of objects to infrared cameras and, more broadly, opportunities for quantum materials in controlling heat transfer.Entities:
Keywords: heat transfer; phase transition; quantum materials; thermal emission; thermal radiation
Year: 2019 PMID: 31848248 PMCID: PMC6936496 DOI: 10.1073/pnas.1911244116
Source DB: PubMed Journal: Proc Natl Acad Sci U S A ISSN: 0027-8424 Impact factor: 11.205