Impact of biomass combustion on occurrence and distribution of aromatic hydrocarbons in apples.

Forest fires and biomass burning are known to generate aromatic hydrocarbons via incomplete combustions, due to high moisture, insufficient temperature, and oxygen content. These emission sources are particularly concerning because generated smokes cannot be treated and aromatic hydrocarbons can deposit on plant foods.The aim of this work was to study the potential deposition and absorption of monocyclic and polycyclic aromatic hydrocarbons in plant after exposure to smokes generated by burning wood. Thus, apples, used as a representative plant food model, were intentionally exposed to wood burning emissions for lengths of time varying from 1 to 2 h. Among benzene, toluene, ethylbenzene, xylenes, toluene appeared to be the most abundant compound. Concerning PAHs, linden wood combustion led to predominant deposition of compounds with molecular weights lower than 202 g/mol with the highest levels detected for phenanthrene.Aromatic hydrocarbons from wood combustion were mainly deposited on apple epicarp, and their transfer to the mesocarp was limited. Diagnostic ratio, used for the determination of PAHs emission source, was calculated with PAHs contents deposited on apple skin. Results were consistent with values proposed in the literature for the identification of biomass combustion.