Highly Efficient Organic Afterglow from a 2D Layered Lead-Free Metal Halide in Both Crystals and Thin Films under an Air Atmosphere.

Organic afterglow materials (OAMs) with a lifetime longer than 0.1 s have recently received much attention for their fascinating properties meeting the critical requirements of applications in newly emerged technologies. However, the development of OAMs lags behind for their low luminescence efficiency. Usually, enhancing the phosphorescence efficiency of organic materials causes a short lifetime. Here, we report two kinds of OAMs, two-dimensional (2D) layered organic-inorganic hybrid zinc bromides (PEZB-NTA and PEZB-BPA), obtained in an environmentally friendly ethanol solvent by a low-temperature solution method. They display highly efficient and persistent luminescence in air in both crystals and thin films with phosphorescence quantum yields up to 42% in crystals and 27% in films. For OAMs, the two quantum yields are the highest values ever reported for crystals and films. Due to the excellent crystalline and film-forming ability, PEZB-NTA and PEZB-BPA in ethanol can be used as inks to construct patterns on various rigid and flexible substrates, including paper, iron, plastic, marble, tin foil, and cloth. Consequently, the novel OAMs show great application prospects in the fields of anti-counterfeiting and information storage because of their economic synthesis, solution processing, and easy operation.