Literature DB >> 31833482

A new iodate-phosphate Pb2(IO3)(PO4) achieving great improvement in birefringence activated by (IO3)- groups.

Xiao-Han Zhang1, Bing-Ping Yang2, Jin Chen2, Chun-Li Hu2, Zhi Fang2, Zujian Wang2, Jiang-Gao Mao2.   

Abstract

The first divalent-metal iodate-phosphate, Pb2(IO3)(PO4), has been prepared via the strategy of introducing (IO3)- into phosphate. The structure features a unique 3D network where [Pb(IO3)]∞+ and [Pb(PO4)]∞- layers are alternatively interconnected. The birefringence of Pb2(IO3)(PO4) is greatly increased to 0.060 at 1064 nm.

Entities:  

Year:  2019        PMID: 31833482     DOI: 10.1039/c9cc08739g

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  1 in total

1.  SrTi(IO3)6·2H2O and SrSn(IO3)6: distinct arrangements of lone pair electrons leading to large birefringences.

Authors:  Kaitong Liu; Jian Han; Junben Huang; Zhonglei Wei; Zhihua Yang; Shilie Pan
Journal:  RSC Adv       Date:  2021-03-10       Impact factor: 3.361

  1 in total

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