Preparation of Boron Nitride-Coated Carbon Fibers and Synergistic Improvement of Thermal Conductivity in Their Polypropylene-Matrix Composites.

The purpose of this study is to prepare boron nitride (BN)-coated carbon fibers (CF) and to investigate the properties of as-prepared fibers as well as the effect of coating on their respective polymer-matrix composites. A sequence of solution dipping and heat treatment was performed to blanket the CFs with a BN microlayer. The CFs were first dipped in a boric acid solution and then annealed in an ammonia-nitrogen mixed gas atmosphere for nitriding. The presence of BN on the CF surface was confirmed using FTIR, XPS, and SEM analyses. Polypropylene was reinforced with BN-CFs as the first filler and graphite flake as the secondary filler. The composite characterization indicates approximately 60% improvement in through-plane thermal conductivity and about 700% increase in the electrical resistivity of samples containing BN-CFs at 20 phr. An increase of two orders of magnitude in the electrical resistivity of BN-CF monofilaments was also observed.