Preparation and application of magnetic biochar in water treatment: A critical review.

In recent years, magnetic biochar has been widely used in removal of pollutants from water. In this paper, the preparation technologies of magnetic biochar are analyzed, and the performance and application of magnetic biochar in removal of inorganic pollutants such as heavy metals, and organic pollutants are investigated. Moreover, the adsorption behaviors, the key influencing factors and the adsorption mechanisms of magnetic biochars are summarized in this paper. Compared with common biochar, magnetic biochar is more effective in removal of water pollutants, including Cd(II), Pb(II), Zn(II), Cu(II), methylene blue, tetracycline, pesticide and phosphate. Langmuir and Freundlich models are adopted as the mainly adsorption isotherms, while pseudo-second-order model is employed as Kinetic model of heavy metal ions and organic contaminants in water. This study also investigates degradation of organic contaminants in water using magnetic biochar as catalyst. Results showed that encapsulated γ-Fe2O3 nanoparticles enhanced the catalytic ability of persulfate activator. Further researches on preparation and application of magnetic biochar in water treatment are prospected in this review.