Literature DB >> 31799586

Recent advances in studies on the magneto-chiral dichroism of organic compounds.

Kazuyuki Ishii1, Shingo Hattori, Yuichi Kitagawa.   

Abstract

Magneto-chiral dichroism (MChD) is an interesting phenomenon in which the absorbance of a chiral molecule depends on the direction of the magnetic field. As the MChD of two enantiomers is opposite in nature, MChD has received considerable attention for the development of magneto-optical devices and new asymmetric synthetic methods, as well as being an explanation for the origin of the homochirality of life. In this perspective, the theoretical background behind MChD is introduced, and then, the first examples of metal complexes and aromatic π-conjugated systems are discussed. Furthermore, the electronic properties of aromatic π-conjugated systems, such as orbital angular momentum and exciton chirality, are theoretically explained, and the possibility of MChD-based photoresolutions is described.

Year:  2020        PMID: 31799586     DOI: 10.1039/c9pp00400a

Source DB:  PubMed          Journal:  Photochem Photobiol Sci        ISSN: 1474-905X            Impact factor:   3.982


  3 in total

1.  Validation of microscopic magnetochiral dichroism theory.

Authors:  M Atzori; H D Ludowieg; Á Valentín-Pérez; M Cortijo; I Breslavetz; K Paillot; P Rosa; C Train; J Autschbach; E A Hillard; G L J A Rikken
Journal:  Sci Adv       Date:  2021-04-21       Impact factor: 14.136

Review 2.  Organic radicals with inversion of SOMO and HOMO energies and potential applications in optoelectronics.

Authors:  Sitthichok Kasemthaveechok; Laura Abella; Jeanne Crassous; Jochen Autschbach; Ludovic Favereau
Journal:  Chem Sci       Date:  2022-07-08       Impact factor: 9.969

3.  Unusual Magnetic Field Responsive Circularly Polarized Luminescence Probes with Highly Emissive Chiral Europium(III) Complexes.

Authors:  Junhui Zhang; Lixiong Dai; Alexandra M Webster; Wesley Ting Kwok Chan; Lewis E Mackenzie; Robert Pal; Steven L Cobb; Ga-Lai Law
Journal:  Angew Chem Int Ed Engl       Date:  2020-11-03       Impact factor: 16.823

  3 in total

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