Literature DB >> 31790113

Synthesis of fluorinated amphoteric organoborons via iodofluorination of alkynyl and alkenyl MIDA boronates.

Wen-Xin Fan1, Ji-Lin Li1, Wen-Xin Lv1, Ling Yang1, Qingjiang Li1, Honggen Wang2.   

Abstract

The iodofluorination of alkynyl and alkenyl MIDA (N-methyliminodiacetyl) boronates led to the synthesis of two types of fluorinated organoborons bearing a valuable C-I bond. The B(MIDA) moiety confers exclusive regioselectivity to the reaction, and the products were formed in generally good yields. Preliminary utility of the products was demonstrated.

Entities:  

Year:  2019        PMID： 31790113     DOI： 10.1039/c9cc08386c

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  3 in total

1.  Regiocontrolled allylic functionalization of internal alkene via selenium-π-acid catalysis guided by boron substitution.

Authors:  Ling Yang; Yuan Liu; Wen-Xin Fan; Dong-Hang Tan; Qingjiang Li; Honggen Wang
Journal:  Chem Sci       Date:  2022-04-22       Impact factor: 9.969

2.  Hypervalent iodine-mediated β-difluoroalkylboron synthesis via an unusual 1,2-hydrogen shift enabled by boron substitution.

Authors:  Wen-Xin Lv; Yin Li; Yuan-Hong Cai; Dong-Hang Tan; Zhan Li; Ji-Lin Li; Qingjiang Li; Honggen Wang
Journal:  Chem Sci       Date:  2022-02-11       Impact factor: 9.825

Review 3.  Recent Advances in the Construction of Fluorinated Organoboron Compounds.

Authors:  Xingxing Ma; Zhijie Kuang; Qiuling Song
Journal:  JACS Au       Date:  2021-12-30
  3 in total

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