Literature DB >> 31764925

A tetranuclear calcium hydride cluster with a highly symmetric [Ca4H6]2+ core.

Danny Schuhknecht1, Thomas P Spaniol, Iskander Douair, Laurent Maron, Jun Okuda.   

Abstract

A highly symmetric, dicationic tetranuclear calcium hydride cluster with an adamantoid [Ca4H6]2+ core stabilized by the NNN macrocycle Me3TACN (1,4,7-trimethyl-1,4,7-triazacyclononane) was prepared. DFT calculations indicate delocalized bonding within the [Ca4H6]2+ fragment with d-orbital contribution.

Entities:  

Year:  2019        PMID： 31764925     DOI： 10.1039/c9cc08540h

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  2 in total

1.  d-d Dative Bonding Between Iron and the Alkaline-Earth Metals Calcium, Strontium, and Barium.

Authors:  Philipp Stegner; Christian Färber; Jan Oetzel; Ulrich Siemeling; Michael Wiesinger; Jens Langer; Sudip Pan; Nicole Holzmann; Gernot Frenking; Uta Albold; Biprajit Sarkar; Sjoerd Harder
Journal:  Angew Chem Int Ed Engl       Date:  2020-07-02       Impact factor: 15.336

2.  Formation and Reactivity of a Hexahydridosilicate [SiH6 ]2- Coordinated by a Macrocycle-Supported Strontium Cation.

Authors:  Thomas Höllerhage; Priyabrata Ghana; Thomas P Spaniol; Ambre Carpentier; Laurent Maron; Ulli Englert; Jun Okuda
Journal:  Angew Chem Int Ed Engl       Date:  2022-01-14       Impact factor: 16.823
  2 in total

北京卡尤迪生物科技股份有限公司 © 2022-2023.