Flow-induced crystallization of biochar in bio-asphalt under various aging conditions.

Flow-induced crystallization (FIC) in polymers is an important problem that occurs on a very rapid time scale. This study aims to evaluate the flow-induced crystallization of bio-asphalt modified with different contents of biochar under various aging conditions. Small angle X-ray scattering and molecular dynamic simulations were performed to impose extensional deformation and the nucleation process. The rheological properties were measured using the dynamic shear rheometer (DSR) and the morphology of biochar modified bio-asphalt (BMBA) was measured using an optical microscope. The relative scattering intensity during crystallization appeared to peak at four strain rates: 13.2 s-1, 19.6 s-1, 25.4 s-1, and 27.3 s-1. The results showed that the addition of biochar could improve the flow-induced crystallization and enhance the high-temperature properties of bio-asphalt. Moreover, crystallization status of BMBA is lamellar crystals. Ultraviolet and pressure aging vessel aging could remarkably affect the crystallization status of BMBA and promote the formation of crystals.