Literature DB >> 31750504

Mixing oil and water with ionic liquids: bicontinuous microemulsions under confinement.

Hojun Kim1, Mengwei Han, Sarith R Bandara, Rosa M Espinosa-Marzal, Cecilia Leal.   

Abstract

We report the structural transition of a phosphonium ionic liquid-based microemulsion from the bulk to nanoconfined between atomically flat micas. Upon the nanoconfinement, we observed a firmly surface-adsorbed ionic liquid film that stabilizes the nanoconfined microemulsion. Further confinement (<11 nm) induces rearrangements in the microemulsion culminating into two well-ordered layers with slow dynamics.

Entities:  

Year:  2019        PMID: 31750504     DOI: 10.1039/c9sm01649j

Source DB:  PubMed          Journal:  Soft Matter        ISSN: 1744-683X            Impact factor:   3.679


  1 in total

1.  Interplay of Polarity and Confinement in Asymmetric Catalysis with Chiral Rh Diene Complexes in Microemulsions.

Authors:  Manuel Kirchhof; Karina Abitaev; Abdulwahab Abouhaileh; Katrin Gugeler; Wolfgang Frey; Anna Zens; Johannes Kästner; Thomas Sottmann; Sabine Laschat
Journal:  Chemistry       Date:  2021-11-23       Impact factor: 5.020

  1 in total

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