| Literature DB >> 31747261 |
Emanuel Hupf1,2, Lorraine A Malaspina1, Sebastian Holsten1, Florian Kleemiss1,3, Alison J Edwards4, Jason R Price5, Valeri Kozich6, Karsten Heyne6, Stefan Mebs6, Simon Grabowsky1,3, Jens Beckmann1.
Abstract
A proximity enforcing diarylsilane ligand is reported, which gives rise to unusual Si-H···M interactions with the d10 metal ions Cu+ and Ag+ upon complexation. These interactions are studied in detail both experimentally and computationally and can be classified to be weakly agostic in nature for the Si-H···Cu interaction. The Si-H···Ag interaction has more signatures of an electrostatic contact.Entities:
Year: 2019 PMID： 31747261 DOI： 10.1021/acs.inorgchem.9b01845
Source DB: PubMed Journal: Inorg Chem ISSN： 0020-1669 Impact factor: 5.165