Aggregation induced emission active fluorescent sensor for the sensitive detection of Hg2+ based on organic-inorganic hybrid mesoporous material.

We report the preparation of an organic-inorganic hybrid mesoporous material, PHC-SBA-15, derived from the coupling of a pyrene-based derivative PHC and mesoporous SBA-15 silica. Compared with the stable aggregation-induced emission (AIE) properties of PHC, those of PHC-SBA-15 were more promoted and active due to the fixation of PHC and the space limitation in mesoporous SBA-15. The aggregation and disaggregation activities can be tuned by controlling the concentrations in aqueous media and changing the fluorescence color from yellow to blue. In addition to the controllable AIE properties, PHC-SBA-15 was applied for the highly selective and sensitive detection of Hg2+ through the fluorescence quenching of monomeric pyrene in aqueous media. The fluorescence intensity at 395 nm was linearly proportional to that of Hg2+ in the concentration ranges of 0-1.0 × 10-5 and 1.0 × 10-5-10 × 10-5 M, showing a low detection limit of 1.02 × 10-7 M. This work provides an effective strategy for modulating the AIE properties from non-active to active by introducing AIE stable molecule into mesoporous silica material. This method also favors the development of fluorescent sensors for detecting targets with high sensitivity and selectivity in aqueous media with less synthetic difficulties.