Application of biosurfactant surfactin as a pH-switchable biodemulsifier for efficient oil recovery from waste crude oil.

Efficient oil separation is the most desirable, but still challenging solution for the waste crude oil problem. This study developed biosurfactant surfactin as a novel pH-switchable biodemulsifier for efficient oil separation. As found, surfactin demulsification achieved a quite well oil separation ratio of over 95% on model emulsions after 20 min at 50 °C. The validity of this demulsification process should be mainly based on the readily lost stabilization ability of surfactin in emulsions triggered by acid addition. Then, surfactin (0.2 g/L) treatment with the aid of ethanol (2%) to improve its distribution could recover over 95% of oil from waste crude oil. After treated by surfactin, the separated oil phase contains tiny water (less than 0.5%) and thus can be reused for resource recycling to reach a compromised balance between satisfying the strict environmental regulations and decreasing the high treatment costs. Hence, in consideration of high demulsification efficiency, environmental-friendly properties and cost-efficiency, surfactin has a great potential for industrial applications for oil recovery from waste crude oil which is a severe problem presents in most of the petroleum-related factories.