Investigation of phase transformations and corrosion resistance in Co/CoCo2O4 nanowires and their potential use as a basis for lithium-ion batteries.

The paper is devoted to the study of the effect of thermal annealing on the change in the structural properties and phase composition of metal Co nanostructures, as well as the prospects of their use as anode materials for lithium-ion batteries. During the study, a four-stage phase transition in the structure of nanowires consisting of successive transformations of the structure (Со-FCC/Co-HCP) → (Со-FCС) → (Со-FCC/СоСо2О4) → (СоСо2О4), accompanied by uniform oxidation of the structure of nanowires with an increase in temperature above 400 °C. In this case, an increase in temperature to 700 °C leads to a partial destruction of the oxide layer and surface degradation of nanostructures. During life tests, it was found that the lifetime for oxide nanostructures exceeds 500 charge/discharge cycles, for the initial nanostructures and annealed at a temperature of 300 °С, the lifetimes are 297 and 411 cycles, respectively. The prospects of using Co/CoCo2O4 nanowires as the basis for lithium-ion batteries is shown.

Introduction

One of the most promising areas for the development of science in the modern world is the creation of nanostructured materials and devices based on them[1-3]. Interest in them is due to the huge potential of using nanostructured materials as catalysts[4,5], drug carriers[6,7], solar cells[8,9], microelectronic devices[10,11], magnetic field sensors, capacitors, etc.[12-15]. A huge variety of shapes of nanostructures such as spheres, wires, dendrites, tubes, cubes, etc. obtained from various types of materials such as carbon, silicon, organic compounds, various metals and their alloys, every year open up more opportunities for creating miniature devices of micro- and nanoscale sizes[7-19]. Of particular interest among various classes of nanomaterials, cylindrical magnetic nanostructures in the form of nanowires or nanotubes occupy a special place. Interest in them is due to their physicochemical, magnetic, and electrical properties, which determine their field of application[20-24]. At the same time, despite the large number of scientific papers related to the study of the physicochemical and structural properties of nanomaterials, as well as methods for their preparation and various methods of modifying properties, this topic is still in demand and relevant among the scientific community[25-30].

The most common method of modifying structural characteristics, as well as carrying out controlled phase transformations, is the method of thermal annealing in various media[31-33]. In most cases, the use of thermal annealing for bulk samples is caused by annihilation of point and vacancy defects in the structure as a result of heating, as well as a decrease in the concentration of distortions and stresses in the structure[34,35]. Another application of thermal annealing is tracking the dynamics of phase transformations and phase transitions in materials, as well as the formation of oxide phases in materials. It is worth noting that the heat treatment method has proven itself not only for massive objects, but also for nanostructured materials, in particular various magnetic nanoparticles and nanostructures, for which heat treatment allows one to initiate phase transformations with subsequent changes in structural and magnetic parameters[36-40]. Moreover, the small sizes of nanostructured materials make it possible to modify the properties in the entire volume of nanostructures, in contrast to bulk materials, in which the uniformity of phase transformations in a large volume is a much labor-consuming task[41,42].

In connection with the above, the goal of this work is to study the effect of thermal annealing on changes in morphological and structural characteristics, as well as the dynamics of phase transformations in cobalt-based nanostructures in the form of nanowires. The interest in cobalt nanostructures and their oxide forms is due to the huge potential for their application in various fields of science and technology, due to their structural parameters and electromagnetic characteristics. As the production method, we chose the method of electrochemical synthesis, which has proven itself as a method of producing nanostructures with controlled geometry, structural parameters, and phase composition[43-47].

Experimenta Part

The production of cobalt-based nanowires was carried out by the method of electrochemical deposition from sulfuric acid electrolyte solution CoSO4 × 7H2O (120 g/l), H3BO (45 g/l), С6Н8О6 (1.5 g/l) in a two-electrode cell, the potential difference during deposition was 1.75 V, growth control and crystal structure formation was carried out using the method of chronoamperograms. The current density during electrochemical deposition was 20 mA/m2. The use of boric and ascorbic acids is due to the maintenance of the required level of acidity of the electrolyte solution, and also allows one to significantly reduce the evolution of hydrogen in the synthesis process[48,49]. For the synthesis of cylindrical nanostructures, template matrices based on Mitsubishi Polyester Film polyethylene terephthalate (Germany) were used, obtained by irradiation with heavy ions of Kr+15 ions with an energy of 1.75 MeV/nucleon with a pore density of 4.0*107 pores/cm2 at the heavy ion accelerator DC- 60 (Nur-Sultan, Kazakhstan). The necessary cylindrical geometry of tracks with a diameter of 400 nm was obtained by chemical etching of irradiated polymer matrices in a solution of sodium hydroxide 85 ± 1°С[50]. After etching, the polymer films were washed and dried. The geometry and density of the etched tracks were controlled using scanning electron microscopy (SEM). To create a conductive layer, a conductive metal layer 0.5 μm thick was sprayed onto one side of the polymer matrix, which served as an electrode for the formation of nanostructures in the pores of the matrix.

The dynamics of phase transformations was carried out using thermal annealing in a muffle furnace at temperatures of 100–700 °C in increments of 100 °C for 8 hours in an air atmosphere. The heating rate was 10°С/min. The samples were cooled along with the furnace. Prior to heat treatment, the samples under study were freed from polymer matrices by their chemical dissolution in a solution of a 5.0 M sodium hydroxide solution for 20 minutes at a temperature of 50°С.

The study of structural and phase transformations as a result of thermal annealing was carried out using the method of X-ray diffraction (diffractometer D8 ADVANCE ECO, Bruker, Karlsruhe, Germany). To evaluate the crystallographic characteristics and phase composition, the Rietveld method and the PDF 2 database were used[51,52].

The study of the elemental composition of nanostructures as a result of synthesis and thermal annealing, as well as the construction of mapping data, was carried out using a «Hitachi TM3030» scanning electron microscope with a «Bruker XFlash MIN SVE» microanalysis system at an accelerating voltage of 15 kV (Hitachi Ltd, Chiyoda, Tokyo, Japan).

Structural and compositional analysis was done with either a JEOL JEM 2100 LaB6 or ARM200F transmission electron microscope (TEM) (JEOL Ltd, Akishima, Tokyo, Japan) operated at 200 kV.

The test of the applicability of synthesized nanostructures before and after thermal modification as anode materials for lithium-ion materials was carried out in CR20 32 two-electrode cells on a charge-discharge test bench CT-3008W-5V (Neware Technology Limited, Zhongkang Rd., Shenzhen, China). As a counter electrode, lithium metal was used. The mass fraction of nanostructures for testing was 0.05 g. Test electrolyte solution: 1 M LiPF6 ethylene carbonate/propylene carbonate/diethyl carbonate/ethyl methyl carbonate/propyl acetate mixture. The anodes were cycled in the galvanostatic mode in the voltage range from 10 mV to 2 V, in the mode of limiting the charging capacity of 1000 mA·h/g[53].

Results and Discussion

Figure 1a–c shows the SEM image of the initial nanowires and the results of the elemental composition of the studied nanowires using the energy dispersive analysis method.

Figure 1

(a) SEM image of synthesized arrays of Co nanowires on substrate. SEM image of synthesized arrays of Co nanowires on a substrate; (b) EDA spectrum of Co nanowires; (c) Results of mapping of the initial nanowire; (d) TEM images from nanowires before and after annealing.

Figure 1a shows an array of synthesized Co nanowires on a substrate. According to the data obtained, it is clear that the initial nanowires repeat the geometry of the tracks of the matrix with high accuracy. The percentage of deformed and broken nanowires, which was calculated by statistical analysis of SEM - images of an array of nanowires located on a metal substrate after removal of the template matrices, is 0.5–1% of the total number of nanowires. A small number of deformed and broken nanostructures indicates a sufficiently large value of the strength characteristics for bending and kink, which are characteristic of polycrystalline nanostructures with a high degree of crystallinity with rigid crystalline and chemical bonds. Figure 1b,c presents the results of studies of the elemental composition and mapping of the initial nanostructures. According to energy dispersive analysis, the initial nanostructures are characterized by the absence of oxygen in the structure, which indicates the absence of oxidative processes and the formation of oxide inclusions in nanowires during synthesis synthesis. Figure 1d shows the dynamics of changes in the surface morphology and internal structure of nanowires as a result of thermal annealing at various temperatures. For the initial nanowires, various texture inclusions are observed, which indicates the polycrystallinity of the nanostructures. It is worth noting that the presence of visible amorphous inclusions and disordered regions is not observed in the structure of the initial nanowires. A detailed analysis of the interplanar distances of regions with different orientations revealed that these regions are characteristic of different phase states of cobalt (face-centered phase (d = 2.16 Å) and hexagonal phase (d = 2.04 Å). For annealed samples at 200 °C, a decrease heterogeneous inclusions in the structure of nanowires. An increase in the irradiation temperature to 400 °C and 700 °C in the surface layer of nanowires results in the formation of amorphous inclusions and their subsequent increase. The presence of such inclusions can be due to oxidation processes, as well as phase transformations.

The study of phase transformations as a result of thermal annealing of nanostructures was carried out using the method of x-ray phase analysis. Figure 2a shows the dynamics of changes in the X-ray diffraction patterns of the studied samples before and after heat treatment. According to x-ray phase analysis, the initial nanowires are polycrystalline structures with several texture orientations, which confirms the data of transmission electron microscopy. The shape and width of the diffraction peaks indicates the presence of distortions and strains in the crystal lattice, as evidenced by the asymmetric shape of the main diffraction peaks. The presence of distortions in interplanar distances is due to synthesis processes and the formation of a crystalline structure during deposition. Using the Rietveld method, as well as assessing the positions of diffraction lines and their intensities, the phase composition of the synthesized nanostructures was determined. Assessment of the phase composition and its dynamics as a result of thermal annealing was carried out using the formula (1)[54]:

Figure 2

(a) X-ray diffraction patterns of nanowires before and after annealing; (b) Phase composition diagrams of the studied structures.

Iphase - average integrated intensity of the main phase of the diffraction line, Iadmixture – average integrated intensity of the additional phase, R – structural coefficient equal to 1.45. The results of the phase composition assessment and the dynamics of its change are presented in the diagrams of Fig. 2b. According to the calculated data, the phase composition of the initial samples is a mixture of two phases: the dominant face-centered (Co-FCC) and hexagonal (Co-HCP), the concentration of which does not exceed 20%. The presence of an impurity hexagonal Со-НCP phase in nanowires is caused by competing crystallite growth processes arising in the synthesis process in different texture directions with the subsequent formation of hexagonal lattices. It should be noted that bulk samples obtained at room temperature are characterized by a hexagonal lattice structure; however, in the case of nanostructures, when the structure is formed in small volumes of the polymer matrix track, the process of the formation of the cubic type of lattices becomes the most energy-efficient. In this case, part of the atoms is formed into a hexagonal structure, as a result of which a solid solution of substitution of two different phases in the structure of the nanowires is formed. The presence of two phases in the structure also leads to additional distortions and deformations of the crystal lattice and interplanar spacings.

For samples of nanostructures subjected to thermal annealing, a change in the intensity, position, and width of diffraction peaks is observed, as well as the appearance of new diffraction peaks for samples annealed at temperatures above 300 °C. According to the data obtained, three characteristic stages of the change in the diffraction patterns of the nanostructures under study can be distinguished. The first stage is characterized by a decrease in the intensities of the contribution of diffraction peaks characteristic of the hexagonal phase of cobalt and its complete absence during annealing of samples at a temperature of 200 °C. In this case, the shift of the diffraction peaks, as well as a change in the shape of the lines characteristic of the face-centered phase of cobalt, indicates a decrease in the concentration of distortions and strains of the crystal lattice, which is due to partial relaxation and annihilation of point defects arising during the synthesis. The second stage of the change is associated with the appearance of new diffraction maxima, which, according to an assessment of their position, are characteristic of the oxide phase СоСо2О4 with a cubic spinel structure and a variable valence of cobalt ions Co3+ and Co2+. The appearance of the oxide phase in the structure is associated with the introduction of oxygen into the surface layers of nanowires, which lead to the introduction of oxygen into the nodes and interstices of the crystal lattice with the subsequent formation of oxide inclusions. It should be noted that the formation of oxide inclusions as a result of the oxidation of Co nanowires above a temperature of 300 °С is in good agreement with the literature data for bulk samples[55,56]. The third phase is characterized by the complete oxidation of nanostructures and the dominance of the СоСо2О4 phase in the structure of nanowires.

Based on the obtained diffraction patterns using the Rietveld method, the basic crystallographic characteristics of nanostructures were determined, the dynamics of which are presented in Table 1.

Table 1

The data of the main crystallographic characteristics.

T, °C	Cell parameter, Å	Crystalline size, nm	Atomic ratio, Co/O at.w. %	Dislocation density, 1015, 1/m2	The concentration of vacancyoxygen defects, %	Integral porosity, %	Dendity, g/cm3
25	Co-FCC – a = 3.5329; Co-HCP – a = 2.4957, c = 4.0533	18.3 ± 2.1	100/0	2.98	0.03	0.53	8.64
100	Co-FCC – a = 3.5142; Co-HCP – a = 2.4816, c = 4.0653	14.6 ± 1.6	100/0	4.71	0.11	0.32	8.71
200	Co-FCC a = 3.5230; Co-HCP – a = 2.4888, c = 4.0701	17.9 ± 1.3	95/5	3.12	0.78	0.25	8.74
300	Co-FCC a = 3.5292; CoCo2O4 –a = 8.0508	16.0 ± 1.5	83/17	3.91	1.82	0.78	7.43
400	Co-FCC a = 3.5230; CoCo2O4 – a = 8.0301	22.6 ± 2.1	78/22	1.96	1.89	1.43	7.02
500	CoCo2O4 – a = 8.0411	31.5 ± 2.5	46/54	1.01	1.98	2.34	6.07
600	CoCo2O4 – a = 8.0364	31.9 ± 2.1	43/57	0.98	2.42	2.54	6.04
700	CoCo2O4 – a = 8.0396	34.9 ± 2.9	41/59	0.81	6.78	7.84	5.89

At low annealing temperatures, which are characterized by a decrease in the contribution of the impurity hexagonal phase in the structure of nanowires, a decrease in the crystal lattice parameters and crystallite sizes is observed, which indicates a decrease in the concentration of defects in the structure of nanowires. Also, a decrease in the concentration of distortions and defects in the structure is indicated by an increase in density and a decrease in the concentration of voids in the crystal lattice. However, a decrease in crystallite size leads to an increase in dislocation defects, and a small penetration of oxygen into the surface layers leads to the appearance of oxygen vacancies in the structure of nanowires. According to the data obtained, an increase in the annealing temperature to 400 °C leads to a sharp increase in the content of the oxide phase in the structure of nanowires, which is caused by an increase in the rate of oxidation of nanowires. As a result of an increase in the annealing temperature and the appearance of oxide inclusions in the structure, an increase in the concentration of vacancy defects and a decrease in the density of nanowires are observed. In this case, an increase in the annealing temperature above 600 °C leads to a sharp decrease in the density of nanowires and an increase in the concentration of porous inclusions and vacancy defects, which may be due to partial degradation of the structure of nanowires as a result of a high oxygen content that can lead to the formation of an oxide shell and the destruction of chemical and crystalline bonds in structure. The most informative values reflecting the degree of perfection of the crystal structure as a result of phase transformations of the type (Со-FСС/Со-HCP) → (Со-FCС) → (Со-FCС/СоСо2О4) → (СоСо2О4 as a result of thermal annealing are the degree of crystallinity of nanostructures (cm Fig. 3a), as well as the concentration of distortions and lattice deformations (see Fig. 3b). These values were obtained by analyzing the shape of the diffraction lines for the presence of amorphous components in them and determining the degree of asymmetry of the diffraction peaks relative to the position of the maxima.

Figure 3

(a) The dynamics of the dependence of the degree of crystallinity of Co nanowires on the annealing temperature; (b) Graph of the change in distortion of the crystal lattice as a result of heat treatment.

According to the obtained dependences, a decrease in the contribution of the hexagonal phase of cobalt leads to an increase in the degree of crystallinity and a decrease in the concentration of distorting factors in the structure. This change occurs due to an increase in the amplitude of thermal vibrations of atoms in the lattice sites with subsequent annihilation of point defects in the structure and a decrease in the concentration of distortions of interplanar distances. In this case, the processes of oxidation of the structure that occur when the temperature rises above 300 °C lead to the appearance of a new oxide phase like spinel, which contributes to an increase in the concentration of distorting factors in the crystal lattice and interplanar spacings, which leads to a decrease in the degree of perfection of the crystal structure. To assess the uniformity of oxidation processes and changes in surface morphology as a result of oxidation, detailed images of the surface of nanowires depending on the annealing temperature were obtained. The data are presented in the form of SEM images and distribution maps of elements in Fig. 4.

Figure 4

Dynamics of changes in morphology and elemental composition based on data from the mapping of Co nanowires depending on the heat treatment mode.

According to the obtained SEM images, it was established that the oxidation processes are associated with the formation of oxide feather-like growths on the surface of nanowires, which are isotropically located on the surface of nanowires. The beginning of the stage of formation of oxide growths is observed at a temperature above 200 °C. In the case of an annealing temperature of 500–600 °C, the surface of the nanowires is uniformly coated with oxide growths whose sizes are from 5 to 10 nm, and oxygen is predominant in the structure of the nanowires, which is also indicated by the elemental composition in Table 1. It should be noted that these results The elemental composition for oxide nanostructures is close to the stoichiometric ratio of oxygen and cobalt for the СоСо2О4 phase. However, an increase in temperature to 700 °C leads to the formation of porous sphere-like inclusions on the surface, which are caused by partial destruction of the oxide layer, while in the vicinity of these inclusions the largest accumulation of oxygen is observed, a high concentration of which can lead to an increase in stresses and distortions of the crystal lattice. The partial destruction of the surface layer of nanowires also confirms the results of a decrease in the degree of crystallinity of nanowires annealed at a temperature of 700 °C.

Among the variety of applications of nanostructured materials, the most popular and promising direction is the search for new materials for creating cathode materials for lithium-ion batteries. It should be noted that in recent years more and more attention has been paid to metal or organometallic nanostructures as the basis for anode materials, which replace the widely used carbon and silicon nanomaterials. Moreover, interest in metal-containing nanomaterials is due to both their geometric and structural features associated with a large specific surface area and high resistance to degradation during lithiation, as well as the presence of a large number of dislocation and vacancy defects that can serve as activation centers for lithiation processes. In turn, nanowires with their cylindrical geometry, having a large concentration of grain boundaries and a developed specific surface, can significantly increase the lifetime of the anode material during operation, as well as the isotropy of structural properties, the ability to control geometry and morphology, the creation of ordered arrays of nanostructures, as well as high strength characteristics make metal and metal-containing nanowires one of the most promising materials for this field. The possibility of a simple method for changing the phase composition and structural properties of nanomaterials as a result of thermal annealing opens up the possibility of increasing the efficiency and life of nanowires.

The prospects of using Со/СоСо2О4 nanowires as an anode material were evaluated on three types of nanostructures: initial nanowires, as well as annealed at temperatures of 300 °C and 500 °C. Figure 5a shows the charge/discharge curves of the 1st cycle of the selected nanostructures during cycling in the 10 mV–3 V mode. For oxide nanostructures, an insignificant increase in the charging capacity is observed, due to the fact that the lithiation processes proceed mainly through oxygen ions, which are also bound by lithium ions, in contrast to the initial structures for which the beginning of lithiation processes is associated with the incorporation of oxygen ions into the structure of the surface layer.

Figure 5

(a) Graph of the curves of the galvanostatic charge-discharge for the initial 5 cycles in the voltage range of 10 mV–3 V. The arrows pointing down indicate the charge (incorporation of lithium into the anode), directed up - discharge (lithium extraction); Dynamics changes in specific capacitance at various charge/discharge speeds (1 С = 195 mA*g−1); (c) A graph of the specific discharge capacity versus the number of cycles tested in the charging capacity mode 1000 mA h/g and SEM images of nanostuctures after testing (in c, the lines indicate the boundary at which the capacity decrease exceeds more than 75%).

Figure 5b shows the dynamics of changes in specific capacitance as a result of changes in the charge/discharge rate C = 195 mA*g−1. The largest specific capacitance at normal charge speed is observed for oxide nanostructures and is 235–240 mAh*g−1, while for initial and annealed at 300 °С, the specific capacitance is 200–205 mAh*g−1 and 220–225 mAh*g−1, respectively. This difference in the specific capacitance value is due to the fact that for oxide nanostructures, lithiation processes are much faster than for cobalt structures, for which lithiation processes are accompanied by the additional formation of oxide inclusions during lithiation. With a change in the charge/discharge rate, it was found that an increase in the charge/discharge speed leads to a decrease in the specific capacitance. However, in case of constant charge/discharge rate, the specific capacitance value is retained. In this case, the reverse decrease in the discharge charge rate for oxide nanostructures leads to the restoration of the specific capacitance to the initial value, which indicates the possibility of changing the charge/discharge rate without material degradation and loss of capacity, while for the initial and annealed at 300 °С recovery specific capacity is 0.4 and 0.8 of the initial value. This decrease is due to oxidative processes and a slight degradation of structural properties during the charge/discharge process.

Figure 5c shows the life test data of the studied nanostructures in the mode of limiting the charging capacity of 1000 mA h/g. As can be seen from the presented data for the initial nanostructures, an increase in the number of cycles of more than 290 leads to a decrease in the specific capacitance, which indicates the beginning of the degradation of the anode material during the tests. It is worth noting that a decrease in the specific capacitance to the limit of 75–80% of the initial value indicates complete degradation of the material and is the boundary limit for determining the lifetime of the anode material. In Fig. 3, a dashed red line marks the boundary after which complete degradation of the material occurs. According to the presented data, oxide nanostructures for which the lifetime exceeds 500 charging/discharging cycles in the limited capacity mode showed the longest life time as a result of resource tests, while for the initial nanostructures and annealed at 300°С, the lifetimes are 297 and 411 cycles, respectively. The insets in Fig. 5c show SEM images of nanostructures after life tests, in which complete or partial degradation of nanowires is observed. The degradation of nanowires is due to a change in the concentration of defects and vacancies in the structure, as well as an increase in the oxygen content during lithiation. Figure 6a,b shows diagrams of changes in the concentration of oxygen vacancies and the degree of crystallinity of nanostructures after life tests, which characterize the degree of degradation of nanostructures. Figure 6c–e shows SEM images and the results of the mapping of nanostructures after reaching the threshold of maximum capacity reduction.

Figure 6

(a) Diagram of changes in the concentration of oxygen vacancies in the structure of nanowires before and after life tests; (b) Chart of crystallinity before and after life tests; (c–e) Results of oxidation and degradation of nanostructures after life tests determined by mapping.

As can be seen from the data presented, the greatest deterioration of the parameters is characteristic of the initial nanowires. In this case, the degradation of nanowires occurs by partial destruction of the structure with the formation of hollow inclusions. The greatest damage is observed for the initial nanostructures, these damages are caused by oxidative processes associated with lithiation and lithium migration during the charge/discharge process. In the presence of deformations and distortions in the structure associated with the presence of an impurity hexagonal phase, the lithiation process occurs from the initial oxidation of the structure necessary for lithium migration. Moreover, the implanted oxygen with a large number of deformations caused by the presence of a metastable hexagonal phase in the structure leads to a sharp deterioration of crystalline and chemical bonds, with the formation of a large number of amorphous inclusions and disordered regions. An increase in the concentration of oxide inclusions and vacancy defects during lithiation leads to the formation of porous inclusions with subsequent complete destruction of the internal structure of nanowires, which is clearly seen in Figs 5c and 6c for the initial samples. In contrast to the initial samples for which the presence of an impurity phase leads to a deterioration of structural properties, annealed samples of nanowires at a temperature of 300 °C show greater resistance to degradation during lithiation. The increase in degradation resistance for annealed nanostructures is due to a decrease in the deformation and distorting contributions to the crystal structure, as well as a high degree of perfection of the crystalline structure in the annealed state. However, as for the initial samples, lithiation processes are associated with the oxidation of the structure during the introduction of oxygen and migration of lithium. As a result, after 400 test cycles, there is a sharp degradation of nanostructures associated with a high concentration of oxide inclusions and the formation of porous inclusions (Fig. 6d,e). In turn, for oxide nanowires obtained as a result of annealing, the presence of an oxide layer on the surface of nanowires leads to the creation of the so-called shell, which is involved in the lithiation process and reduces the rate of degradation of nanostructures.

Table 2 presents the results of a comparative analysis of the resource tests of the obtained nanostructures with other cobalt oxide nanostructures.

Table 2

Comparative analysis of the results with literature data.

Structure type	Authors	Resource tests	Main results
Co3O4/graphene hybrid anode in the form of nanoparticles whose average size did not exceed 5 nm.	Haegyeom Kim et al.[57]	Tests for the study of the reversibility of the specific capacitance depending on the charge/discharge rate	It has been established that the Co3O4/graphene-based anode material provides a reversible capacity of more than 800 mAh*g−1 at a speed of 200 mA*g−1 in the voltage range from 3.0 to 0.001 V. It is also shown that the value of the reversible capacity remains at elevated densities current. At current speeds up to 1000 mA * g−1, the anode material based on Co3O4/graphene has a reversible capacity of more than 550 mAh*g−1, which is significantly higher than the capacity of modern graphite anodes.
Co3O4 nanostructures of nanoparticles, nanocubes, and hierarchical pompon-like microspheres	Guo B. et al.[58]	Tests to determine the dependence of the change in specific discharge capacity on the number of cycles	During life tests, it was found that the pompon-like Co3O4 microspheres show the highest discharge capacity (980–1000 mAh*g−1) and the longest life time as an anode material (more than 50 cycles).
Co3O4@graphene Composites	Baojun Li et al.[59]	Tests to determine the dependence of the change in specific discharge capacity on the number of cycles.	As a result of tests, it was found that the performance of nanostructures during testing in the regime of 60 cycles showed good stability and charge/discharge rate. At the same time, CGC structures demonstrated improved intercalation properties of lithium ions, with a specific discharge capacity of 941 mAh*g−1, in the first cycle and 740 мА mAh*g−1, after 60 cycles (which corresponds to 88.3% of the initial value).
Arrays of Co3O4 Nanowires	Li Y. et al.[60]	Tests for the study of the reversibility of the specific capacitance depending on the charge/discharge rate	During the life tests of arrays of oxide nanowires, it was found that at a current of 1 C, arrays of nanowires retain a capacitance of 700 mAh*g−1 after 20 discharge/charge cycles. With an increase in the charge rate to 50 °C, the specific capacitance value remains within 50% of the initial value.
Co3O4 Hollow Microspheres	Wang, J. et al.[61]	Tests for the study of the reversibility of the specific capacitance depending on the charge/discharge rate	During life tests as anode materials, the hollow Co3O4 microspheres showed excellent throughput, good cycling performance and ultra-high specific capacity (1615.8 mAh*g−1 at the 30th cycle). Superior performance in the casting process is ensured by a porous hollow multilayer microstructure.
The initial nanowires, as well as annealed at temperatures of 300 °C and 500 °C.	Our work	Tests for the study of the reversibility of the specific capacitance depending on the charge/discharge rate	It was established that the longest life time as a result of life tests was shown by oxide nanostructures for which the lifetime is more than 500 charge/discharge cycles, for the initial nanostructures and annealed at a temperature of 300 °C, the lifetimes are 297 and 411 cycles, respectively. The largest value of specific capacity at normal charge speed is observed for oxide nanostructures and is 235–240 mAh*g−1, for initial and annealed at 300°С the value of specific capacity is 200–205 mAh*g−1 and 220–225 mAh*g−1, respectively.

As can be seen from the data presented in a comparative review of cobalt oxide nanostructures, they are one of the most attractive materials for the anode materials of lithium-ion batteries. It should be noted that in most cases, high values of specific capacitance and lifetime are associated with a high degree of crystallinity, as well as a developed specific surface that has a significant effect on the conductive properties of nanomaterials. As most authors of[57-61] note, cobalt oxide nanostructures can compete in the future with silicon, carbon, and graphene structures in alternative energetics and new energy sources.

Conclusion

The paper presents the results of a study of the effect of thermal annealing on the phase changes of Co nanowires, as well as assessing the prospects of their use as anode materials for lithium-ion batteries. The initial samples are cylindrical polycrystalline nanowires whose phase composition is a mixture of two phases - the dominant face-centered (Co-FCC) and hexagonal (Co-HCP), the concentration of which is no more than 20%. According to x-ray phase analysis data, a four-stage process of phase transformations in nanostructures (Со-FСС/Co-HCP) → (Со-FCС) → (Со-FCС/СоСо2О4) → (СоСо2О4) during annealing was determined. It was determined that the oxidation processes are associated with the formation of oxide feather-like growths on the surface of nanowires, which are isotropically located on the surface of nanowires. During life tests, it was found that the lifetime for oxide nanostructures exceeds 500 charge/discharge cycles, for the initial nanostructures and annealed at a temperature of 300°С, the lifetimes are 297 and 411 cycles, respectively. The largest specific capacitance at normal charge speed is observed for oxide nanostructures - 235–240 mAh*g−1, for initial and annealed at 300°С nanostructures, the specific capacitance is 200–205 mAh*g−1 and 220–225 mAh*g−1 respectively. It was found that a decrease in the specific capacity and lifetime of the anode material is due to an increase in the concentration of oxide inclusions and vacancy defects during lithiation in the structure of nanowires, which leads to the formation of porous inclusions with subsequent complete destruction of the internal structure of nanowires. The prospects of using nanostructures as the basis for anode materials are shown lithium ion batteries.