Gas-Phase Formation of 1-Methylcyclopropene and 3-Methylcyclopropene via the Reaction of the Methylidyne Radical (CH; X2Π) with Propylene (CH3CHCH2; X1A').

The crossed molecular beam reactions of the methylidyne radical (CH; X2Π) with propylene (CH3CHCH2; X1A') along with (partially) substituted reactants were conducted at collision energies of 19.3 kJ mol-1. Combining our experimental data with ab initio electronic structure and statistical calculations, the methylidyne radical is revealed to add barrierlessly to the carbon-carbon double bond of propylene reactant resulting in a cyclic doublet C4H7 intermediate with a lifetime longer than its rotation period. These adducts undergo a nonstatistical unimolecular decomposition via atomic hydrogen loss through tight exit transition states forming the cyclic products 1-methylcyclopropene and 3-methylcyclopropene with overall reaction exoergicities of 168 ± 25 kJ mol-1. These C4H6 isomers are predicted to exist even in low-temperature environments such as cold molecular clouds like TMC-1, since the reaction is barrierless and exoergic, all transition states are below the energy of the separated reactants, and both the methylidyne radical (CH; X2Π) and propylene reactant were detected in cold molecular clouds such as TMC-1.