Oxidative potential of ambient PM2.5 in Wuhan and its comparisons with eight areas of China.

Oxidative potential (OP) is a good indicator for assessing health risk associated with exposure to fine particulate matter (PM2.5, <2.5 μm in aerodynamic diameter). In this study, 24-h ambient PM2.5 samples were collected at three sampling sites throughout selected months of 2012 in Wuhan, Central China. Water soluble ions, metals, organic carbon (OC), elemental carbon (EC), levoglucosan, polycyclic aromatic hydrocarbons (PAHs), hopanes, and dicarboxylic acids were determined. The dithiothreitol (DTT) assay was used to characterize the oxidative potential of PM2.5. Linear regression analysis and principal component analysis (PCA) were used to link OP to the individual redox-active components originating from diverse emission sources. The OP results from the three sites in Wuhan, combined with the findings from eight other field studies of OP conducted in China, were compiled in order to compare the OP data in developed countries. The average, normalized OP levels for volume and mass at the three sampling sites in Wuhan were in the range of 1.8-8.2 nmol min-1 m-3 and 18.2-52.8 nmol min-1 mg-1, respectively. The differences in OP levels across sampling sites depended on the temporal and spatial differences in redox-active components of PM2.5. Results from linear regression and PCA showed that the redox-active components emitted from secondary inorganic aerosols as well as secondary organic aerosols were associated with the volume normalized OP in Wuhan. Two notable findings are illustrated by synthesizing the OP results observed at multi-sites across China. Of the nine field studies conducted in China, the lowest measured mass-normalized OP levels are significantly higher than the highest OP levels from field studies conducted in developed continents. China shares the same sources responsible for OP (e.g., secondary sources, fuel combustion, biomass burning, and dust emissions) with several other countries in developed continents.