Literature DB >> 31681922

Synthesis of a two-dimensional organic-inorganic bismuth iodide metalate through in situ formation of iminium cations.

Natalie Dehnhardt1, Jan-Niclas Luy, Marvin Szabo, Mirco Wende, Ralf Tonner, Johanna Heine.   

Abstract

(Me2C[double bond, length as m-dash]NMe2)Bi2I7 represents a new layered organic-inorganic iodido bismuthate. It displays an unprecedented anion topology, a low band gap and good stability. Advanced electronic structure analysis finds the II interactions to be decisive for the compound's structural and electronic properties.

Entities:  

Year:  2019        PMID： 31681922     DOI： 10.1039/c9cc06625j

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  2 in total

1.  Multiple Roles of 1,4-Diazabicyclo[2.2.2]octane in the Solvothermal Synthesis of Iodobismuthates.

Authors:  Yunhe Cai; Ann M Chippindale; Richard J Curry; Paz Vaqueiro
Journal:  Inorg Chem       Date:  2021-03-22       Impact factor: 5.165

2.  Assembling Polyiodides and Iodobismuthates Using a Template Effect of a Cyclic Diammonium Cation and Formation of a Low-Gap Hybrid Iodobismuthate with High Thermal Stability.

Authors:  Tatiana A Shestimerova; Andrei V Mironov; Mikhail A Bykov; Anastasia V Grigorieva; Zheng Wei; Evgeny V Dikarev; Andrei V Shevelkov
Journal:  Molecules       Date:  2020-06-15       Impact factor: 4.411
  2 in total

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