Literature DB >> 31674787

Regio- and Diastereoselective Copper-Catalyzed Carbometalation of Cyclopropenylsilanes.

Yair Cohen1, Ilan Marek1.   

Abstract

We therein report a regio- and diastereoselective copper-catalyzed carbometalation of enantioenriched readily available cyclopropenylsilanes as a synthetic tool to access a large family of stereodefined fully-(hexa)-substituted cyclopropanes.

Entities:  

Year:  2019        PMID： 31674787     DOI： 10.1021/acs.orglett.9b03531

Source DB:  PubMed          Journal:  Org Lett        ISSN： 1523-7052            Impact factor:   6.005


  7 in total

1.  Enantioselective Hydrothiolation: Diverging Cyclopropenes through Ligand Control.

Authors:  Shaozhen Nie; Alexander Lu; Erin L Kuker; Vy M Dong
Journal:  J Am Chem Soc       Date:  2021-04-15       Impact factor: 15.419

2.  Mechanistic Insights on the Selectivity of the Tandem Heck-Ring-Opening of Cyclopropyldiol Derivatives.

Authors:  Anthony Cohen; Alexander Kaushansky; Ilan Marek
Journal:  JACS Au       Date:  2022-03-05

3.  Stereospecific Construction of Quaternary Carbon Stereocenters from Quaternary Carbon Stereocenters.

Authors:  Kaushalendra Patel; Veeranjaneyulu Lanke; Ilan Marek
Journal:  J Am Chem Soc       Date:  2022-04-12       Impact factor: 16.383

4.  Stereoinvertive Nucleophilic Substitution at Quaternary Carbon Stereocenters of Cyclopropyl Ketones and Ethers.

Authors:  Xu Chen; Ilan Marek
Journal:  Angew Chem Int Ed Engl       Date:  2022-05-11       Impact factor: 16.823

5.  Preparation of Distant Quaternary Carbon Stereocenters by Double Selective Ring-Opening of 1,1-Biscyclopropyl Methanol Derivatives.

Authors:  Yogesh Siddaraju; Juliette Sabbatani; Anthony Cohen; Ilan Marek
Journal:  Angew Chem Int Ed Engl       Date:  2022-05-20       Impact factor: 16.823

6.  Regio- and Diastereoselective Carbometalation Reaction of Cyclopropenes.

Authors:  Yair Cohen; Ilan Marek
Journal:  Acc Chem Res       Date:  2022-09-14       Impact factor: 24.466

7.  Stereoselective Synthesis of Polysubstituted Spiropentanes.

Authors:  Yair Cohen; Dor Toledano; Ilan Marek
Journal:  J Am Chem Soc       Date:  2022-09-11       Impact factor: 16.383
  7 in total

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