Literature DB >> 31656962

The first two examples of halogen bonding with a sigma hole-donating fluorine in the Csp3-FOsp3 interaction from polyfluorinated trans-dihalo-palladium(ii) di-substituted pyridine complexes.

Vijayanath Elakkat1, Chu-Chun Chang, Jun-Yu Chen, Yung-Cheng Fang, Chia-Rui Shen, Ling-Kung Liu, Norman Lu.   

Abstract

The first two examples of halogen bonding in the Csp3-FOsp3 interaction have been both experimentally and theoretically proved for trans-[PdX2(3-HCF2CF2CH2OCH2py)2] complexes where X = Cl and Br. Both metal complexes with a Csp3-FOsp3 halogen bond have a σ hole donating fluorine.

Entities:  

Year:  2019        PMID： 31656962     DOI： 10.1039/c9cc06731k

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  2 in total

1.  Recoverable Phospha-Michael Additions Catalyzed by a 4-N,N-Dimethylaminopyridinium Saccharinate Salt or a Fluorous Long-Chained Pyridine: Two Types of Reusable Base Catalysts.

Authors:  Eskedar Tessema; Vijayanath Elakkat; Chiao-Fan Chiu; Jing-Hung Zheng; Ka Long Chan; Chia-Rui Shen; Peng Zhang; Norman Lu
Journal:  Molecules       Date:  2021-02-22       Impact factor: 4.411

2.  Synthesis and cationic polymerization of halogen bonding vinyl ether monomers.

Authors:  Yudai Morota; Takanaga Suzuki; Kira B Landenberger
Journal:  RSC Adv       Date:  2022-01-20       Impact factor: 3.361
  2 in total

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