Literature DB >> 31637387

Highly stereoselective intramolecular Buchner reaction of diazoacetamides catalyzed by a Ru(ii)-Pheox complex.

Nga Phan Thi Thanh1, Masaya Tone1, Hayato Inoue1, Ikuhide Fujisawa1, Seiji Iwasa1.   

Abstract

This work reports the first efficient enantioselective intramolecular Buchner reaction of diazoacetamides. The Ru(ii)-Pheox catalyst was shown to be highly efficient in this transformation in terms of both the regio- and enantioselectivity (up to 99% ee) giving the desired products in quantitative yield.

Entities:  

Year:  2019        PMID： 31637387     DOI： 10.1039/c9cc06889a

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  3 in total

1.  Hypervalent iodine promoted the synthesis of cycloheptatrienes and cyclopropanes.

Authors:  Da-Fu Yuan; Zi-Chen Wang; Rui-Sen Geng; Guang-Yi Ren; James S Wright; Shao-Fei Ni; Ming Li; Li-Rong Wen; Lin-Bao Zhang
Journal:  Chem Sci       Date:  2021-12-08       Impact factor: 9.825

Review 2.  Uncommon carbene insertion reactions.

Authors:  Ming-Yao Huang; Shou-Fei Zhu
Journal:  Chem Sci       Date:  2021-11-02       Impact factor: 9.825

3.  Rh2(ii)-catalyzed enantioselective intramolecular Büchner reaction and aromatic substitution of donor-donor carbenes.

Authors:  Dong Zhu; Tongxiang Cao; Kai Chen; Shifa Zhu
Journal:  Chem Sci       Date:  2022-01-19       Impact factor: 9.825
  3 in total

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