Effect of thiourea-modified biochar on adsorption and fractionation of cadmium and lead in contaminated acidic soil.

Biochar was obtained through pyrolysis of carrot pulp (CP) and then further modified with thiourea (CH4N2S). We investigated the effect of carrot pulp biochar (CPB) and modified CPB (MCPB) for adsorption and chemical fractionation of cadmium (Cd) and lead (Pb) in contaminated acidic soil. Application of modified biochar significantly (p < 0.05) increased the pH, soil organic carbon (SOC), and cation exchange capacity (CEC) of the soil, especially at the 8% application rate. The adsorption equilibrium data showed that the adsorption behavior of Cd and Pb could be described more reasonably by the pseudo-second-order kinetic model and the Langmuir isotherm model more accurately fitted the experimental data than Freundlich and Temkin isotherm models. The maximum adsorption capacity of soil treated with MCPB at the 8% application rate for Cd and Pb were 4122.7 and 5219.6 mg kg-1, respectively. Sequential chemical extractions revealed that incorporation soil with MCPB induced the transformation of the acid-soluble fraction of Cd to oxidizable and residual fractions, and the acid-soluble fraction of Pb to reducible, oxidizable, and residual fractions. The results demonstrated that the application of MCPB could effectively immobilize Cd and Pb, thereby reducing their mobility in contaminated acidic soil.