| Literature DB >> 31621325 |
Gayan B Wijeratne1, Mayukh Bhadra1, Maxime A Siegler1, Kenneth D Karlin1.
Abstract
A cuprous chelate bearing a secondary sphere hydrogen bonding functionality, [(PV-tmpa)CuI]+, transforms •NO(g) to N2O(g) in high-yields in methanol. Ligand derived proton transfer facilitates N-O bond cleavage of a putative hyponitrite intermediate releasing N2O(g), underscoring the crucial balance between H-bonding capabilities and acidities in (bio)chemical •NO(g) coupling systems.Entities:
Year: 2019 PMID: 31621325 PMCID: PMC6896986 DOI: 10.1021/jacs.9b07286
Source DB: PubMed Journal: J Am Chem Soc ISSN: 0002-7863 Impact factor: 15.419