Literature DB >> 31617513

Photochemical hydrogen evolution from water by a 1D-network of octahedral Ni6L8 cages.

Kilaparthi Sravan Kumar1, Vishwanath S Mane2, Ashok Yadav1, Avinash S Kumbhar2, Ramamoorthy Boomishankar3.   

Abstract

A self-assembled M6L8 type cage-connected 1D-coordination network of formula {[Ni6(MeSi(3py)3)8Cl9(H2O)2]Cl3·16H2O}∞ (1) was obtained from a 3-pyridyl substituted silane ligand MeSi(3py)3. This complex shows significantly high performance for the electrocatalytic and photocatalytic hydrogen evolution reaction (HER) in water. A maximum turnover number (TON) of 2824 has been observed for photocatalytic HER after 69 h.

Entities:  

Year:  2019        PMID: 31617513     DOI: 10.1039/c9cc06286f

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  2 in total

1.  Cation- and Anion-Mediated Supramolecular Assembly of Bismuth and Antimony Tris(3-pyridyl) Complexes.

Authors:  Álvaro García-Romero; Jose M Martín-Álvarez; Daniel Miguel; Dominic S Wright; Celedonio M Álvarez; Raúl García-Rodríguez
Journal:  Inorg Chem       Date:  2021-12-09       Impact factor: 5.165

2.  Direct Z-Scheme Heterojunction Catalysts Constructed by Graphitic-C3N4 and Photosensitive Metal-Organic Cages for Efficient Photocatalytic Hydrogen Evolution.

Authors:  Chuying Lv; Su Qin; Yang Lei; Xinao Li; Jianfeng Huang; Junmin Liu
Journal:  Nanomaterials (Basel)       Date:  2022-03-07       Impact factor: 5.076

  2 in total

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