| Literature DB >> 31608909 |
Carolin Dee1, Francesco Zinna2, Winald R Kitzmann3, Gennaro Pescitelli2, Katja Heinze3, Lorenzo Di Bari2, Michael Seitz1.
Abstract
The chiral spin-flip luminophore [Cr(ddpd)2]3+ can be resolved into enantiopure material by chiral HPLC. The corresponding enantiomers show very high luminescence dissymmetry factors of up to ∣glum ∣≈ 0.093 in circularly polarized luminescence (CPL) measurements for the "ruby-like" phosphorescence transition 2E/2T1 → 4A2 in the near-IR region around λ ≈ 775 nm.Entities:
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Year: 2019 PMID: 31608909 DOI: 10.1039/c9cc06909g
Source DB: PubMed Journal: Chem Commun (Camb) ISSN: 1359-7345 Impact factor: 6.222