Literature DB >> 31608576

Synthesis and Characterization of 3-(5-(Fluorodinitromethyl)-1H-1,2,4-triazol-3-yl)-4-nitrofurazan: A Novel Promising Energetic Component of Boron-based Fuels for Rocket Ramjet Engines.

Aleksei B Sheremetev1, Natali S Aleksandrova1, Svyatoslav S Semyakin1, Kyrill Yu Suponitsky2, David B Lempert3.   

Abstract

The synthesis of a new energetic 1,2,4-triazole compound bearing nitrofurazanyl and fluorodinitromethyl units, which may find use as a component for rocket ramjet engines (RRE), is described. The target product was prepared in a four-step process applying oxidation/nitration/decarboxylation/fluorination reactions and is fully characterized. Its density and structural features were uniquely determined by X-ray analysis. It is shown that replacing HMX with the compound of this study in boron-based fuels gives an increase in energy.
© 2019 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Entities:  

Keywords:  boron-based fuels; energetic materials; fluorodinitromethyl; furazan; triazole

Year:  2019        PMID: 31608576     DOI: 10.1002/asia.201901280

Source DB:  PubMed          Journal:  Chem Asian J        ISSN: 1861-471X


  2 in total

1.  Synthesis of 3-Aryl-ortho-carboranes with Sensitive Functional Groups.

Authors:  Sergey A Anufriev; Akim V Shmal'ko; Kyrill Yu Suponitsky; Igor B Sivaev
Journal:  Molecules       Date:  2021-12-01       Impact factor: 4.411

2.  Novel family of nitrogen-rich energetic (1,2,4-triazolyl) furoxan salts with balanced performance.

Authors:  Alexander A Larin; Alla N Pivkina; Ivan V Ananyev; Dmitry V Khakimov; Leonid L Fershtat
Journal:  Front Chem       Date:  2022-09-12       Impact factor: 5.545

  2 in total

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