Literature DB >> 31593354

Vapor-Phase Linker Exchange of the Metal-Organic Framework ZIF-8: A Solvent-Free Approach to Post-synthetic Modification.

João Marreiros1, Lenz Van Dommelen1, Guillaume Fleury1, Rodrigo de Oliveira-Silva1, Timothée Stassin1, Paul Iacomi2, Shuhei Furukawa3, Dimitrios Sakellariou1, Philip L Llewellyn2, Maarten Roeffaers1, Rob Ameloot1.   

Abstract

Zeolitic imidazolate frameworks (ZIFs) are a sub-class of metal-organic frameworks (MOFs). Although generally stable, ZIFs can undergo post-synthetic linker exchange (PSLE) in solution under mild conditions. Herein, we present a novel, solvent-free approach to post-synthetic linker exchange through exposure to linker vapor.
© 2019 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Entities:  

Keywords:  ZIF-8; metal-organic frameworks; mixed-linker ZIFs; solvent-free modification; vapor-phase linker exchange

Year:  2019        PMID： 31593354     DOI： 10.1002/anie.201912088

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN： 1433-7851            Impact factor:   15.336


  1 in total

1.  Hybrid Benzimidazole-Dichloroimidazole Zeolitic Imidazolate Frameworks Based on ZIF-7 and Their Application in Mixed Matrix Membranes for CO2/N2 Separation.

Authors:  Qian Jia; Elsa Lasseuguette; Magdalena M Lozinska; Maria-Chiara Ferrari; Paul A Wright
Journal:  ACS Appl Mater Interfaces       Date:  2022-10-04       Impact factor: 10.383
  1 in total

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