Literature DB >> 31584737

Access to Enantiopure Advanced Intermediates en Route to Madangamines.

Celeste Are1, Maria Pérez2, Roberto Ballette1, Stefano Proto1, Federica Caso1, Nihan Yayik1, Joan Bosch1, Mercedes Amat1.   

Abstract

The synthesis of enantiopure ABCE and ABCD tetracyclic advanced intermediates en route to madangamine alkaloids and studies for the construction of the triunsaturated 15-membered D ring of madangamine B and the saturated 13-membered D ring of madangamine E are reported.
© 2019 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Entities:  

Keywords:  alkaloids; macrocycles; madangamines; skipped dienes; total synthesis

Year:  2019        PMID: 31584737     DOI: 10.1002/chem.201904045

Source DB:  PubMed          Journal:  Chemistry        ISSN: 0947-6539            Impact factor:   5.236


  1 in total

1.  A New Organocatalytic Desymmetrization Reaction Enables the Enantioselective Total Synthesis of Madangamine E.

Authors:  Shinya Shiomi; Benjamin D A Shennan; Ken Yamazaki; Ángel L Fuentes de Arriba; Dhananjayan Vasu; Trevor A Hamlin; Darren J Dixon
Journal:  J Am Chem Soc       Date:  2022-01-17       Impact factor: 15.419

  1 in total

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