Literature DB >> 31574742

Characterization of the non-Arrhenius behavior of supercooled liquids by modeling nonadditive stochastic systems.

A C P Rosa Junior1, C Cruz1, W S Santana1, M A Moret2,3.   

Abstract

The characterization of the formation mechanisms of amorphous solids is a large avenue for research, since understanding its non-Arrhenius behavior is challenging to overcome. In this context, we present one path toward modeling the diffusive processes in supercooled liquids near glass transition through a class of nonhomogeneous continuity equations, providing a consistent theoretical basis for the physical interpretation of its non-Arrhenius behavior. More precisely, we obtain the generalized drag and diffusion coefficients that allow us to model a wide range of non-Arrhenius processes. This provides a reliable measurement of the degree of fragility of the system and an estimation of the fragile-to-strong transition in glass-forming liquids, as well as a generalized Stokes-Einstein equation, leading to a better understanding of the classical and quantum effects on the dynamics of nonadditive stochastic systems.

Year:  2019        PMID: 31574742     DOI: 10.1103/PhysRevE.100.022139

Source DB:  PubMed          Journal:  Phys Rev E        ISSN: 2470-0045            Impact factor:   2.529


  2 in total

1.  From the Kinetic Theory of Gases to the Kinetics of Rate Processes: On the Verge of the Thermodynamic and Kinetic Limits.

Authors:  Valter H Carvalho-Silva; Nayara D Coutinho; Vincenzo Aquilanti
Journal:  Molecules       Date:  2020-04-30       Impact factor: 4.411

2.  Modified Arrhenius Equation in Materials Science, Chemistry and Biology.

Authors:  Jan Kohout
Journal:  Molecules       Date:  2021-11-26       Impact factor: 4.411

  2 in total

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