Photocatalytic Approaches for Hydrogen Production via Formic Acid Decomposition.

The photocatalytic dehydrogenation of formic acid has recently emerged as an outstanding alternative to the traditional thermal catalysts widely applied in this reaction. The utilization of photocatalytic processes for the production of hydrogen is an appealing strategy that perfectly matches with the idea of a green and sustainable future energy scenario. However, it sounds easier than it is, and great efforts have been needed to design and develop highly efficient photocatalysts for the production of hydrogen from formic acid. In this work, some of the most representative strategies adopted for this application are reviewed, paying particular attention to systems based on TiO2, CdS and C3N4.