Literature DB >> 31517365

CO2 activation by manganese pincer complexes through different modes of metal-ligand cooperation.

Amit Kumar1, Prosenjit Daw, Noel Angel Espinosa-Jalapa, Gregory Leitus, Linda J W Shimon, Yehoshoa Ben-David, David Milstein.   

Abstract

We report here the activation of CO2 using two Mn-PNN pincer complexes that can exhibit different modes of metal-ligand cooperation amido/amino mode that involves [1,2]-activation of CO2 and dearomatization/aromatization mode that involves [1,3]-activation of CO2. We also compare their catalytic activity for CO2 hydrogenation.

Entities:  

Year:  2019        PMID： 31517365     DOI： 10.1039/c9dt03088c

Source DB:  PubMed          Journal:  Dalton Trans        ISSN： 1477-9226            Impact factor:   4.390


  7 in total

1.  Manganese-Catalyzed Hydrogenation of Ketones under Mild and Base-free Conditions.

Authors:  Stefan Weber; Julian Brünig; Luis F Veiros; Karl Kirchner
Journal:  Organometallics       Date:  2021-04-22       Impact factor: 3.876

2.  Carbon Dioxide Hydrogenation to Formate Catalyzed by a Bench-Stable, Non-Pincer-Type Mn(I) Alkylcarbonyl Complex.

Authors:  Sylwia Kostera; Stefan Weber; Maurizio Peruzzini; Luis F Veiros; Karl Kirchner; Luca Gonsalvi
Journal:  Organometallics       Date:  2021-04-20       Impact factor: 3.876

3.  Controlling the Product Platform of Carbon Dioxide Reduction: Adaptive Catalytic Hydrosilylation of CO2 Using a Molecular Cobalt(II) Triazine Complex.

Authors:  Hanna H Cramer; Basujit Chatterjee; Thomas Weyhermüller; Christophe Werlé; Walter Leitner
Journal:  Angew Chem Int Ed Engl       Date:  2020-06-02       Impact factor: 15.336

4.  Selective Room-Temperature Hydrogenation of Amides to Amines and Alcohols Catalyzed by a Ruthenium Pincer Complex and Mechanistic Insight.

Authors:  Sayan Kar; Michael Rauch; Amit Kumar; Gregory Leitus; Yehoshoa Ben-David; David Milstein
Journal:  ACS Catal       Date:  2020-04-21       Impact factor: 13.084

5.  Metal-Ligand Cooperativity of the Calix[4]pyrrolato Aluminate: Triggerable C-C Bond Formation and Rate Control in Catalysis.

Authors:  Fabian Ebner; Lukas Maximilian Sigmund; Lutz Greb
Journal:  Angew Chem Int Ed Engl       Date:  2020-08-18       Impact factor: 15.336

Review 6.  Sustainable catalysis with fluxional acridine-based PNP pincer complexes.

Authors:  Sayan Kar; David Milstein
Journal:  Chem Commun (Camb)       Date:  2022-03-18       Impact factor: 6.222

7.  Systematic Variation of 3d Metal Centers in a Redox-Innocent Ligand Environment: Structures, Electrochemical Properties, and Carbon Dioxide Activation.

Authors:  Niklas W Kinzel; Derya Demirbas; Eckhard Bill; Thomas Weyhermüller; Christophe Werlé; Nicolas Kaeffer; Walter Leitner
Journal:  Inorg Chem       Date:  2021-12-01       Impact factor: 5.165
  7 in total

北京卡尤迪生物科技股份有限公司 © 2022-2023.