Literature DB >> 31506989

Controlled Heterometallic Composition in Linear Trinuclear [LnCeLn] Lanthanide Molecular Assemblies.

Verónica Velasco1,2, Leoní A Barrios1,2, Mike Schütze1, Olivier Roubeau3, Fernando Luis3, Simon J Teat4, David Aguilà1,2, Guillem Aromí1,2.   

Abstract

The combination of two different β-diketone ligands facilitates the size-controlled assembly of pure heterometallic [LnLn'Ln] linear compounds thanks to two different coordination sites present in the molecular scaffold. [HoCeHo], [ErCeEr], and [YbCeYb] analogues are presented here and are characterized both in the solid state and in solution, demonstrating the selectivity of this unique method to produce heterometallic 4f molecular entities.
© 2019 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Entities:  

Keywords:  coordination chemistry; heterometallic complexes; lanthanides; ligand design; quantum computing

Year:  2019        PMID: 31506989     DOI: 10.1002/chem.201903829

Source DB:  PubMed          Journal:  Chemistry        ISSN: 0947-6539            Impact factor:   5.236


  2 in total

1.  Unparalleled selectivity and electronic structure of heterometallic [LnLn'Ln] molecules as 3-qubit quantum gates.

Authors:  Diamantoula Maniaki; Diego Garay-Ruiz; Leoní A Barrios; Daniel O T A Martins; David Aguilà; Floriana Tuna; Daniel Reta; Olivier Roubeau; Carles Bo; Guillem Aromí
Journal:  Chem Sci       Date:  2022-04-14       Impact factor: 9.969

2.  A heterometallic [LnLn'Ln] lanthanide complex as a qubit with embedded quantum error correction.

Authors:  Emilio Macaluso; Marcos Rubín; David Aguilà; Alessandro Chiesa; Leoní A Barrios; Jesús I Martínez; Pablo J Alonso; Olivier Roubeau; Fernando Luis; Guillem Aromí; Stefano Carretta
Journal:  Chem Sci       Date:  2020-08-20       Impact factor: 9.969

  2 in total

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