Toward Imperfection-Insensitive Soft Network Materials for Applications in Stretchable Electronics.

Development of stretchable devices with mechanical responses that mimic those of biological tissues/organs is of particular importance for the long-term biointegration, as the discomfort induced by the mechanical mismatch can be minimized. Recent works have established the bioinspired designs of soft network materials that can precisely reproduce the unconventional J-shaped stress-strain curves of human skin at different regions. Existing studies mostly focused on the design, fabrication, and modeling of perfect soft network materials. When utilized as the substrates of biointegrated electronics, the soft network designs, however, often need to incorporate deterministic holes, a type of imperfection, to accommodate hard, inorganic electronic components. Understanding of the effect of hole imperfections on the mechanical properties of soft network materials is thereby essential in practical applications. This paper presents a combined experimental and computational study of the stretchability and elastic modulus of imperfect soft network materials consisting of circular holes with a variety of diameters. Both the size and location of the circular-hole imperfections are shown to have profound influences on the stretchability. Based on these results, design guidelines of imperfection-insensitive network materials are introduced. For the imperfections that result in an evident reduction of stretchability, an effective reinforcement approach is presented by enlarging the width of horseshoe microstructures at strategic locations, which can enhance the stretchability considerably. A stretchable and imperfection-insensitive integrated device with a light-emitting diode embedded in the network material serves a demonstrative application.