Literature DB >> 31498595

New Bisoxazoline Ligands Enable Enantioselective Electrocatalytic Cyanofunctionalization of Vinylarenes.

Niankai Fu1, Lu Song1, Jinjian Liu1, Yifan Shen1, Juno C Siu1, Song Lin1.   

Abstract

In contrast to the rapid growth of synthetic electrochemistry in recent years, enantioselective catalytic methods powered by electricity remain rare. In this work, we report the development of a highly enantioselective method for the electrochemical cyanophosphinoylation of vinylarenes. A new family of serine-derived chiral bisoxazolines with ancillary coordination sites were identified as optimal ligands.

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Year:  2019        PMID： 31498595      PMCID： PMC7023682          DOI： 10.1021/jacs.9b03296

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  57 in total

1.  Aminoxyl-Catalyzed Electrochemical Diazidation of Alkenes Mediated by a Metastable Charge-Transfer Complex.

Authors:  Juno C Siu; Joseph B Parry; Song Lin
Journal:  J Am Chem Soc       Date:  2019-01-28       Impact factor: 15.419

2.  A Dual-Catalytic Strategy To Direct Asymmetric Radical Aminotrifluoromethylation of Alkenes.

Authors:  Jin-Shun Lin; Xiao-Yang Dong; Tao-Tao Li; Na-Chuan Jiang; Bin Tan; Xin-Yuan Liu
Journal:  J Am Chem Soc       Date:  2016-07-20       Impact factor: 15.419

3.  Phosphinoyl Radical-Initiated α,β-Aminophosphinoylation of Alkenes.

Authors:  Jian-An Li; Pei-Zhi Zhang; Kui Liu; Adedamola Shoberu; Jian-Ping Zou; Wei Zhang
Journal:  Org Lett       Date:  2017-08-23       Impact factor: 6.005

4.  Metal-catalyzed electrochemical diazidation of alkenes.

Authors:  Niankai Fu; Gregory S Sauer; Ambarneil Saha; Aaron Loo; Song Lin
Journal:  Science       Date:  2017-08-11       Impact factor: 47.728

5.  Electrooxidative Amination of sp2 C-H Bonds: Coupling of Amines with Aryl Amides via Copper Catalysis.

Authors:  Subban Kathiravan; Subramanian Suriyanarayanan; Ian A Nicholls
Journal:  Org Lett       Date:  2019-02-20       Impact factor: 6.005

6.  Enantioselective Copper-Catalyzed Intermolecular Amino- and Azidocyanation of Alkenes in a Radical Process.

Authors:  Dinghai Wang; Fei Wang; Pinghong Chen; Zhenyang Lin; Guosheng Liu
Journal:  Angew Chem Int Ed Engl       Date:  2017-01-23       Impact factor: 15.336

Review 7.  Recent developments in the synthesis and utilization of chiral β-aminophosphine derivatives as catalysts or ligands.

Authors:  Wenbo Li; Junliang Zhang
Journal:  Chem Soc Rev       Date:  2016-03-21       Impact factor: 54.564

8.  Modulation of multifunctional N,O,P ligands for enantioselective copper-catalyzed conjugate addition of diethylzinc and trapping of the zinc enolate.

Authors:  Fei Ye; Zhan-Jiang Zheng; Wen-Hui Deng; Long-Sheng Zheng; Yuan Deng; Chun-Gu Xia; Li-Wen Xu
Journal:  Chem Asian J       Date:  2013-06-18

9.  Electrochemical Azidooxygenation of Alkenes Mediated by a TEMPO-N3 Charge-Transfer Complex.

Authors:  Juno C Siu; Gregory S Sauer; Ambarneil Saha; Reed L Macey; Niankai Fu; Timothée Chauviré; Kyle M Lancaster; Song Lin
Journal:  J Am Chem Soc       Date:  2018-09-12       Impact factor: 15.419

10.  Amino Acid-Derived Bifunctional Phosphines for Enantioselective Transformations.

Authors:  Tianli Wang; Xiaoyu Han; Fangrui Zhong; Weijun Yao; Yixin Lu
Journal:  Acc Chem Res       Date:  2016-06-16       Impact factor: 22.384
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  7 in total

Review 1.  Catalyzing Electrosynthesis: A Homogeneous Electrocatalytic Approach to Reaction Discovery.

Authors:  Juno C Siu; Niankai Fu; Song Lin
Journal:  Acc Chem Res       Date:  2020-02-20       Impact factor: 22.384

2.  Electroreductive Carbofunctionalization of Alkenes with Alkyl Bromides via a Radical-Polar Crossover Mechanism.

Authors:  Wen Zhang; Song Lin
Journal:  J Am Chem Soc       Date:  2020-11-24       Impact factor: 15.419

3.  Electrochemically driven regioselective C-H phosphorylation of group 8 metallocenes.

Authors:  Hao Zheng; Chang-Hui Liu; Shi-Yu Guo; Gu-Cheng He; Xiang-Ting Min; Bo-Chao Zhou; Ding-Wei Ji; Yan-Cheng Hu; Qing-An Chen
Journal:  Nat Commun       Date:  2022-06-17       Impact factor: 17.694

4.  Electrophotocatalytic Undirected C-H Trifluoromethylations of (Het)Arenes.

Authors:  Youai Qiu; Alexej Scheremetjew; Lars H Finger; Lutz Ackermann
Journal:  Chemistry       Date:  2020-02-19       Impact factor: 5.236

Review 5.  Organic Electrochemistry: Molecular Syntheses with Potential.

Authors:  Cuiju Zhu; Nate W J Ang; Tjark H Meyer; Youai Qiu; Lutz Ackermann
Journal:  ACS Cent Sci       Date:  2021-03-09       Impact factor: 14.553

6.  Palladium-catalyzed asymmetric allylic 4-pyridinylation via electroreductive substitution reaction.

Authors:  Weijie Ding; Mengfan Li; Jinkun Fan; Xu Cheng
Journal:  Nat Commun       Date:  2022-09-26       Impact factor: 17.694

Review 7.  New Redox Strategies in Organic Synthesis by Means of Electrochemistry and Photochemistry.

Authors:  Jinjian Liu; Lingxiang Lu; Devin Wood; Song Lin
Journal:  ACS Cent Sci       Date:  2020-07-16       Impact factor: 14.553
  7 in total

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