| Literature DB >> 31486470 |
David L Burnett1, Ryan Oozeerally, Ralentri Pertiwi, Thomas W Chamberlain, Nikolay Cherkasov, Guy J Clarkson, Yuni K Krisnandi, Volkan Degirmenci, Richard I Walton.
Abstract
Yb6(BDC)7(OH)4(H2O)4 contains both bridging hydroxyls and metal-coordinated waters, possessing Brønsted and Lewis acid sites. The material crystallises from water at 200 °C. Using the solid as a heterogenous catalyst, glucose is converted into 5-hydroxymethylfurfural, via fructose, with a total selectivity of ∼70% after 24 hours at 140 °C in water alone: the material is recyclable with no loss of crystallinity.Entities:
Year: 2019 PMID： 31486470 DOI： 10.1039/c9cc05364f
Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222