Literature DB >> 31486436

Enantioselective organocatalytic activation of vinylidene-quinone methides (VQMs).

Jean Rodriguez1, Damien Bonne.   

Abstract

Vinylidene-quinone methides (VQMs) are highly electrophilic chiral reagents that can be generated in situ from 2-(phenylethynyl)phenols. They were characterized for the first time in 2012 but their enantioselective organocatalytic activation was addressed only very recently. Their specific reactivity has revealed innovative strategies notably for the control of axial chirality.

Entities:  

Year:  2019        PMID： 31486436     DOI： 10.1039/c9cc05097c

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  3 in total

Review 1.  Catalytic, Enantioselective Sulfenofunctionalization of Alkenes: Development and Recent Advances.

Authors:  Anastassia Matviitsuk; Jesse L Panger; Scott E Denmark
Journal:  Angew Chem Int Ed Engl       Date:  2020-08-18       Impact factor: 15.336

2.  Organocatalytic atroposelective construction of axially chiral N, N- and N, S-1,2-azoles through novel ring formation approach.

Authors:  Yu Chang; Chuandong Xie; Hong Liu; Shengli Huang; Pengfei Wang; Wenling Qin; Hailong Yan
Journal:  Nat Commun       Date:  2022-04-11       Impact factor: 14.919

3.  Bidirectional enantioselective synthesis of bis-benzofuran atropisomeric oligoarenes featuring two distal C-C stereogenic axes.

Authors:  Xiaoze Bao; Jean Rodriguez; Damien Bonne
Journal:  Chem Sci       Date:  2019-11-20       Impact factor: 9.825
  3 in total

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