| Literature DB >> 31478550 |
Luke O'Brien1, Somnath Narayan Karad, William Lewis, Hon Wai Lam.
Abstract
The synthesis of functionalized 1-tetralones by the rhodium(i)-catalyzed reaction of alkynyl malonates with arylboronic acids is described. These arylative cyclizations proceed via an alkenyl-to-aryl 1,4-Rh(i) migration as a key step. Preliminary results of an enantioselective variant of these reactions are also presented.Entities:
Year: 2019 PMID： 31478550 DOI： 10.1039/c9cc05205d
Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222