Literature DB >> 31465017

Correction to "Thermally Crosslinked Functionalized Polydicyclopentadiene with a High T g and Tunable Surface Energy".

Tyler J Cuthbert, Jun Chen, Fraser P Burns, Matthew G Moffitt, Jeremy E Wulff.   

Abstract

[This corrects the article DOI: 10.1021/acsomega.6b00193.].

Entities:  

Year:  2017        PMID: 31465017      PMCID: PMC6641188          DOI: 10.1021/acsomega.7b00685

Source DB:  PubMed          Journal:  ACS Omega        ISSN: 2470-1343


In determining the glass transition temperature (Tg) for our functionalized polydicyclopentadiene material, we were unfortunately misled by a calibration artifact associated with our DSC instrument, which caused us to report the incorrect value. We regret this error and would like to provide the correct DSC data and Tg here. As shown in Figure , the true Tg value for our methyl ester-functionalized polydicyclopentadiene (polymer 6 in our original paper[1]) is 172 ± 3 °C (average data from 4 runs, acquired on two separate instruments). Although this is considerably lower than our earlier reported value, it remains the highest reported Tg for an unaged[2−4] polydicyclopentadiene material. As such, our conclusions in the published paper remain valid.
Figure 1

Corrected differential scanning calorimetry (DSC) data for crosslinked, methyl ester-functionalized polydicyclopentadiene. Data were collected using a heating rate of 10 °C/min.

Corrected differential scanning calorimetry (DSC) data for crosslinked, methyl ester-functionalized polydicyclopentadiene. Data were collected using a heating rate of 10 °C/min.
  2 in total

1.  Thermal properties of ruthenium alkylidene-polymerized dicyclopentadiene.

Authors:  Yuval Vidavsky; Yotam Navon; Yakov Ginzburg; Moshe Gottlieb; N Gabriel Lemcoff
Journal:  Beilstein J Org Chem       Date:  2015-08-21       Impact factor: 2.883

2.  Thermally Crosslinked Functionalized Polydicyclopentadiene with a High T g and Tunable Surface Energy.

Authors:  Jun Chen; Fraser P Burns; Matthew G Moffitt; Jeremy E Wulff
Journal:  ACS Omega       Date:  2016-10-06
  2 in total

北京卡尤迪生物科技股份有限公司 © 2022-2023.