Field Study on Correlation between CO2 Concentration and Surface Soil CO2 Flux in Closed Coal Mine Goaf.

Self-heating of coal mine goaf or shallow coal seams can release an outbreak of unimaginable pollution disaster under suitable circumstances. As an indicator gas, CO2 is always used to determine the coal spontaneous combustion state during the self-heating process. Based on this, the paper investigated the influence of abandoned coal mine goaf CO2 on the surface environment by measuring the CO2 concentration in the borehole connected to the goaf and CO2 flux on the soil surface. Furthermore, rainfall and atmospheric temperature effects are discussed to illustrate the correlation between the CO2 concentration and surface soil CO2 flux in the closed mine goaf. Subsequently, the tracer gas experimental method is employed to analyze the effect of air leakage from an open-pit slope on CO2 flux. The experimental results demonstrated that the distribution of CO2 concentration in the borehole confirms the continuous diffusion of goaf CO2 onto the surface. The value of CO2 flux in the goaf is significantly higher than that of a normal area. Temperature is one of the primary factors that affect the CO2 flux on the field. Air leakage from the slope promotes the surface soil-overlying goaf CO2 diffusion. The study provides important reference data for the assessment of the mining area field environment and the determination of the spontaneous combustion risk of the residual coal in the goaf.

Introduction

Coal has been the primary energy resource in China. For a long time, the large-scale exploitation of coal resources has led to an increase in the area of goaf created by underground mining. At the same time, the influence of the underground mined-out area has gradually emerged on the surrounding environment. On the one hand, the toxic and harmful gases are generated by the spontaneous combustion of residual coal remained in the closed goaf and then diffused to the surface, which affects the surface flora, fauna, and shallow microbes, thereby affecting the ecological environment of the area. On the other hand, by the action of high temperature and high pressure in the deep, the CO2 gas in the closed goaf migrates to the surface. During this process, CO2 gas can dissolve the shallow groundwater that affects its characteristics by changing the pH and directly or indirectly affect the surface soil–plant ecosystem.[1−3] Therefore, the research on correlation between the underground coal-generated CO2 concentration and surface soil CO2 flux has become more and more important.

At present, the study on the characteristics of spontaneous combustion in the goaf mainly includes the beam tube monitoring method, tracer gas method, infrared thermometer method, temperature sensor method, etc.[4] There are many factors, such as high cost, complex implementation, and difficult installation, and so on, which make it difficult to carry out. Meanwhile, the research on the influence of the harmful gases generated by spontaneous combustion in the goaf on its overlying surface and the analysis of spontaneous combustion characteristics in the goaf by the change in surface CO2 emission concentration has not been carried out. Based on this, on the premise of analyzing the spontaneous combustion characteristics and the gas diffusion law in the closed goaf, the emission law of CO2 from the overlying surface of the goaf and its influencing factors were measured and analyzed by the intelligent soil gas monitoring system combined with tracer gas monitoring equipment. Then, the effects of CO2 concentration in the closed goaf on the changes of surface CO2 flux and fluctuation laws were discussed in the paper.

Experimental Apparatus and Procedure

Outline of Measurement

Surface CO2 flux measurement is mostly used in environmental science studies to investigate respiration characteristics of surface soil, vegetation, and soil microorganisms.[5−7] Previous studies show that, during the whole process from coal low-temperature oxidation to high-temperature pyrolysis, the reaction that produced CO2 takes up a large proportion in each stage.[8−11] Therefore, it is feasible to take CO2 as an indicator gas to determine the oxidation state of goaf residual coal or shallow coal seam. The dynamic factors that promote the goaf surface soil CO2 diffusion process are as follows: (i) Mining process destroyed the original geological structure and formed a large number of fissures, which is conducive to the CO2 diffusion; (2) the goaf residual coal oxidized or smoldered to generate heat, making the goaf ambient temperature increase benefitting the gas emission; (3) overlying strata collapse increases the goaf pressure, which is conducive to the CO2 emission. In addition, the respiration of microorganisms and plant roots on the ground surface that produces CO2 is affected by environmental conditions. It is clearly different from the gas diffusion from the goaf. An approach to the prediction of coal spontaneous combustion is presented under the assumption that the surface soil CO2 flux can directly reflect the oxidation state of underground coal. In this study, the surface soil CO2 flux, environmental temperature, and wind velocity were measured continuously by the soil gas flux monitoring system. The CO2 flux characteristics including the fluctuation rule were analyzed to clarify the differences between the fields of the normal area and over the goaf.

However, surface CO2 flux overlying the goaf is dominated mainly by the oxidation of residual coal remaining in the goaf. The results show that, in the process of CO2 diffusion to the surface, some of CO2 will dissolve in the underground aquifer; a small amount of CO2 will be fixed by the rock medium or by microorganisms and plants near the surface; and most of CO2 produced by spontaneous combustion in the goaf will diffuse to the surface.[12,13] Therefore, the flux change of surface CO2 can indirectly reflect the spontaneous combustion state of the goaf. Studying the variation law of surface CO2 flux can effectively analyze the spontaneous combustion process of residual coal in the goaf.

The surface soil CO2 flux is the amount of CO2 gas emission per unit area and unit time, which is defined aswhere F is the gas flux (mol·m–2·s–1), ρ is the standard state gas density (kg·m–3), V is the gas chamber volume (m3), A is the surface area of CO2 emission (m2), M is the gas molecular weight (g·mol–1), Ct is the linear increase in CO2 concentration in parts per million (10–6), Δt is the time step (s), g is the gravitational acceleration (m·s–2), P is the absolute pressure of the measuring point (Pa), P0 is the standard atmospheric pressure, T is the temperature of the measuring point (K), and T0 is the standard state temperature (K).

The characteristics of CO2 emission were monitored by the closed chamber method in the field measurements.[14] In this study, a constant volume automatic ventilation chamber (HL-1017B) was used to measure the gas exchange flux between the soil and the atmosphere environment. By drilling holes on the surface of the goaf to monitor the distribution of CO2 concentration in the borehole with a multichannel gas analyzer (SKY2000-M3), the emission and diffusion characteristics of CO2 in the goaf are analyzed. The tracer gas technique was used to find out the source and route of air leakage in the slope of the test area and verify the influence of air leakage on the variation of goaf surface CO2 flux.

Field Measurement Methodology

The targeted field is located on the overlying surface of the mined-out area including goafs on the east side, about 150 m away from the Haizhou Open-Pit Mine, as shown in Figure . The Haizhou Open-Pit Mine is 3 km away from the Fuxin City center. The mining area is 4 km long from east to west and 2 km wide from north to south. The Haizhou Open-Pit Mine 250 m deep and involves a total area of 30 km2 was closed and stopped its production. The average annual rainfall in this area is 539 mm, and the evaporation is 1800 mm. It is a semi-arid continental monsoon climate zone in the north temperate zone.[15] The soil type in the mining area is composed mainly of cinnamon soil; the sandy soil layer is about 3.0–5.5 m in thickness. The content of the organic matter is 1.2–1.5%, and the soil pH value is between 7.1 and 7.5.

Figure 1

Map of measurement locations.

As shown in Figure , the measurement locations on the surface area are as follows: the #0 point on normal soil in is an unmined area, #2 and #3 points are on the surface over the goaf, and the #1 point is a wellbore 80 m in depth, which connects to the goaf. Also, the diameter of the wellbore upper part (H ≤ 6 m) is 27 cm. The layout of monitoring points in the borehole is shown in Figure . There are six coal seams in the location. From the bottom to the top are Gaode 3, Gaode 2, 1.0 m, 2.5 m, 1.5 m, and 1.3 m coal seams, respectively. Among them, the 1, 1.5, and 2.5 m coal seams are not mined, and the coal seam elevation is between −75 and −30 m (ground elevation is about +180 m). About 70 m on the west side of the measuring point is the Gaode 2 chasm. The geological condition of the monitoring points and surface soil properties and atmospheric parameters of the measuring area are shown in Tables and , respectively.

Figure 2

CO2 concentration in the borehole connecting to the goaf.

Table 1

Geological Condition of the Monitoring Points

serial number	altitude (m)	adjacent fault	coal seam name	coal seam elevation (m)	mined out area (Y/N)	distance from slope (m)
#1	+183	no. 2 fault	1.3 m	0 to +25	Y	about 150
			1.5 m	–30 to +20	N
			2.5 m	–30 to −20	Y
			Gaode 2	–50 to −60	Y
#2	+179	no. 1 fault	1.3 m	+120 to +130	N	about 100
			1.5 m	+120 to +130	N
			2.5 m	+120 to +130	Y
			Gaode 2	+20 to +30	Y
#3	+180	nos. 1 and 2 faults	1.3 m	+25 to +40	Y	about 23
			1.5 m	+10 to +40	N
			2.5 m	–10 to +25	Y
			Gaode 2	–100 to −75	Y

Table 2

Surface Soil and Atmospheric Parameters

serial number	relative humidity (%)	volume weight of soil (g·cm–3)	soil porosity (%)
#0	20–80	1.85	29
#1	44–67	1.70	32
#2	54–70	1.95	26
#3	40–64	1.90	27

In this study, the long-term monitoring method of the surface CO2 flux was carried at #0, #2, and #3 points (Figure ). The surface CO2 fluxes at #0, #2, and #3 points were measured by the closed chamber method. The effect of spontaneous combustion in the goaf was investigated by continuous monitoring of the soil surface CO2 flux.

Figure 3

Site maps of measuring points and measuring instruments.

Furthermore, the short-term measurement of the CO2 concentration versus the depth of the borehole at the #1 point was carried out using the open measuring principle. The relationship between air leakage into the goaf and CO2 flux changes was studied using the SF6 laser leak detector (KARAT LLD-100) to verify the effect of air leakage at the #3 point. SF6 as a tracer gas was released continuously from the surface at the lower part of the open-pit mine slope. The vertical distance from the monitoring point is 30 m, and the horizontal distance is 120 m. The locations of the releasing and monitoring points are shown in Figure . To avoid the data contingency caused by the single point measurement, two test points and two blank points were selected to measure the SF6 concentration. The test points I and II for the measurements were located over the fracture zone, and the blank points (points III and IV) for measurements are 30 cm away from the test points. The SF6 concentrations of the points were compared to verify the air leakage from the open-pit mine slope.

Figure 4

Tracer gas measurement for air leakage detection.

Results and Discussion

CO2 Emission Characteristics of the Overlying Surface at the Normal Area

To investigate the CO2 flux changes in the soil overlying the goaf, the CO2 flux at the normal area (#0 point) was measured as shown in Figure . It was observed that the CO2 flux of the #0 measuring point is high in the daytime and low at night. The reason is basically consistent with the change in soil temperature. The surface soil of the measurement area is composed of sandstone and coal powder. The soil is relatively dry, and there is no vegetation on the surface. The measured surface CO2 flux between 0.1 and 0.2 μmol·m–2·s–1 is mainly emission from the respiration of microorganisms in the soil. A low temperature inhibits soil microbial respiration, and high soil moisture prevents the diffusion of CO2.[16] Therefore, the lowest surface flux emission in the daytime occurs around 6 a.m. with the lowest temperature and relatively high humidity. In this monitoring area, the soil is dry. Accordingly, the CO2 flux increased sharply during the period of rainfall. According to the measurement results, the appropriate rainfall will lead to a large increase in the surface CO2 flux. This kind of increase does not occur immediately but starts approximately 2 h after rainfall. This is a process in which rainwater penetrates into the soil and causes decomposition and buffering of the microorganisms and organic matter in the soil. The elapsed time of the CO2 flux starts to rise up until the peak value is about 3 h. With continuous rainfall, the soil water content on the surface will inhibit CO2 emission.

Figure 5

Surface CO2 flux at the normal area during 1 week at the #0 point.

Analysis of Surface CO2 Flux over Goaf

The CO2 fluxes measured at #2 and #3 points are shown in Figures and , respectively. The CO2 flux at the #2 point is about 0.25–1.25 μmol·m–2·s–1, which is 5–10 times larger than that of the normal area (about 10% of #3 point test data). The goaf under the #2 point was created about 30 years ago, and the surface has subsided due to free collapse. The goaf is in a closed state and does not have coal spontaneous combustion; therefore, the measured value of the surface flux is relatively low.

Figure 6

Tests result of the #2 point (15 days).

Figure 7

Tests result of the #3 point (15 days).

The spontaneous combustion phenomenon in the goaf under the #3 point is obvious. Due to the short distance, air leakage from the slope to the goaf may induce residual coal spontaneous combustion. The test results of the CO2 flux at the #3 point are shown in Figure . The surface CO2 flux range is 10–15 μmol·m–2·s–1. The variation of CO2 flux is still correlated with the daily temperature changes, and the fluctuation of CO2 flux is much larger than that of the normal area. These results indicate that the daily variation of CO2 flux is not only affected by the biological activity but also related to the air leakage intensity caused by diurnal temperature differences.

Figure shows the temperature and CO2 flux curves of the day and night (24 h). It can be seen that the CO2 flux of the normal area (#0 measuring point) has the same trend as the temperature changes (see Figure a). The CO2 flux increases with increasing atmospheric temperature. However, Figure b,c shows that the CO2 flux on the surface over the goaf is negatively correlated with the atmospheric temperature. The #2 point is located over the goaf but does not include the spontaneous combustion of coal. However, the CO2 flux is still 5–10 times larger than that of the normal area, indicating that, due to the influence of internal and external temperatures and pressure differences, there is still existing goaf CO2 continuous emission to the surface. The mined-out area of this measuring point was created for a long time and collapsed freely. The goaf interior is approximately confined, the air leakage is weak, and the temperature is constant.

Figure 8

Curves of CO2 daily emission: (a) #0 point, (b) #2 point, and (c) #3 point.

During the summer period, the temperature difference between the goaf and the outside reduces with increasing atmospheric temperature. So, it weakens the diffusion of CO2 due to less buoyancy force on the gas.[17,18] Therefore, surface CO2 flux increases as the temperature decreases. CO2 emission of the #3 point is significantly higher than that of the #2 point and affected by the temperature change. The change in air leakage intensity caused by the temperature difference has a significant effect on the oxidation reaction of residual coal in the goaf and the gas diffusion intensity from the goaf to the surface. These relations indicate that the oxidizing reaction intensity of residual coal in the goaf affects indirectly the value of surface soil CO2 flux.

Seasonal Changes in Surface CO2 Fluxes over Goaf

The surface soil CO2 emission under different seasonal conditions is measured as shown in Figures and . The same time period (9:00 a.m. to 12:00 p.m. in sunny daytime), winter (December), and summer (July) monitoring results were selected to compare the effect of season changes on CO2 flux.

Figure 9

Monitoring results at the #2 point in summer.

Figure 10

Monitoring results at the #2 point in winter.

The soil animals, plants, soil microflora, and other soil organisms show significant differences in the living conditions due to the temperature difference between winter and summer (the average temperature difference is about 40 °C). In summer, the measured CO2 flux in the goaf-overlying surface contains both CO2 released by soil fauna and soil microflora activities and the CO2 diffused from the goaf. However, in winter, the life activities of surface soil fauna and microflora are almost stopped since the atmospheric temperature drops below the freezing point. Based on this, it has become apparent that the oxidation state of the underground coal can be indirectly determined by monitoring the change in the surface CO2 flux.

Due to the seasonal changes, the fluctuation law of CO2 flux on the surface of the #2 point shows quite different trends. Comparing Figures and can conclude that, in the same test period, the CO2 flux fluctuation range is small, and the variation curve is relatively flat in summer; however, the CO2 flux increases with temperature in winter. In summer, the atmospheric temperature is high, and the metabolic activities of soil animals, plants, soil microflora, and other soil organisms in the surface soil are frequent. The slow oxidation stage of the residual coal in the goaf accelerates the release of CO2; therefore, the total measured CO2 flux is relatively high.[19,20] Consequently, the measured CO2 flux is about 1 time larger than that in winter. However, during the summer monitoring period, due to the small relative temperature difference between the goaf and the outside, the surface CO2 flux varies slightly (as shown in Figure ), which is not conducive to the diffusion of CO2 to the surface. Therefore, when the temperature is at the highest level, the change in surface CO2 flux is not obvious. In winter tests, the measured CO2 flux range is 0.2 to 0.3 μmol·m–2·s–1, much lower than the measured summer data. In a cold environment, the soil fauna and soil microflora activities almost stopped, and there is no extra CO2 emission. The measured CO2 flux is only from the goaf diffusion. Additionally, the #2 point underground goaf is closed; the temperature is higher than that of the outside atmosphere, resulting in a large temperature and pressure difference between the goaf and the outside, which accelerates the CO2 release to the surface. So, the surface CO2 flux increased with increasing outside atmospheric temperature, as shown in Figure . From the discussion, one may conclude that the difference in environmental conditions such as temperature and soil characteristics is the main reason for the different trends of CO2 flux on the surface soil. By measuring the CO2 flux overlying the goaf, the conditions of underground coal can be indirectly reflected, which lays a data foundation for more accurately predicting and warning the residual coal in the abandoned goaf and the spontaneous combustion state of the shallow buried coal seam.

Tracer Gas Measurement for Air Leakage Pass

To confirm the air leakage to the goaf from the open-pit mine slope, the tracer gas measurement was carried out. Before the release of SF6, the background concentrations of the points (test points I and II and blank test points III and IV) were determined. After the values were stabilized, SF6 was continuously released. The wind velocity is measured every 5 min. The change in SF6 concentration and the distribution of wind velocity are shown in Figures and .

Figure 11

Relationship between the SF6 concentration and wind velocity at points I and II.

Figure 12

Relationship between the SF6 concentration and wind velocity at points II and IV.

As shown in Figure , the measured SF6 background concentration is in the range of 5–18 ppb. The elapsed time of test point I that detected the SF6 concentration rise was 50 min, and the peak value reached 110 ppb. According to the measured wind velocity, the stronger the wind velocity, the higher the measured SF6 concentration. Since SF6 is released in the slope, to eliminate the influence of diffusion in the atmosphere, the blank test point III is simultaneously measured, and the concentration change is also illustrated in Figure . When moved to the blank test point III, the concentration of SF6 instantaneously drops below 18 ppb, returning to the background concentration measured before release.

As can be seen from Figures and , the crack position at the test point II is relatively wide, and a peak concentration value of 230 ppb appears when the wind velocity is up to the maximum. When the wind velocity drops, the concentration value also decreases. Finally, the SF6 concentration in the test point II is stable at about 120 ppb. Once the monitoring probe to the blank test point IV was moved, the SF6 concentration drops below 18 ppb.

Combining the results of Figures and , we can see that a certain concentration of SF6 can be detected at the surface crack of the goaf. The measured SF6 concentration is directly proportional to the wind velocity, indicating that the goaf has air leakage in the slope and the stronger the wind velocity, the more air leakage to the goaf. Air leakage promotes the oxidation of residual coal in the goaf, which increases the concentration of internal CO2 and speeds up its diffusion to the surface. According to the comparative analysis of the measured results of test points I and II and blank test points III and IV, it can be seen that most of SF6 released from the slope penetrates into the goaf with the air leakage. The surface cracks connect to the goaf, and the air leakage on the slope promotes the CO2 emission from the overlying surface.

Correlation Analysis of Surface CO2 Emission and Goaf Spontaneous Combustion

To study the diffusion process of CO2 from the goaf to the surface and fully understand the variation of the underground CO2 concentration, the emission characteristics of CO2 from the borehole connecting to the goaf were measured by infrared gas monitoring equipment. In the measurement, nine monitoring positions were set at the #1 point (see Figure ). Each monitoring takes 6 min and operates 11 cycles throughout the day.

Summarizing the data measured in Figure , the CO2 concentration in the borehole deeper part is higher than that in the upper part. However, when H > 1 m, the CO2 concentration almost remains constant. Meanwhile, the larger the depth, the smaller the fluctuation of the monitored CO2 concentration. According to Fick’s law and the measured climate data, atmospheric temperature is the most important reason for this phenomenon. Moreover, it also points out that the CO2 concentration in the borehole below 1 m depth is not affected by changes in atmospheric temperature. The measurement results indirectly prove the existence of CO2 diffusion from the goaf to the surface. When the region exceeds 2 m in depth, the CO2 concentration has a decreasing trend with increasing depth, as shown in Figure .

Figure 13

Relationship of the CO2 concentration and temperature changes at different depths: (a) H = 0.4 m, (b) H = 0.6 m, (c) H = 0.8 m, (d) H = 1 m, (e) H = 2 m, (f) H = 3 m, and (g) H = 5 m.

The change in the CO2 concentration is positively correlated with the ambient temperature, as shown in Figure . The higher the ambient temperature, the stronger the CO2 diffusion ability. Therefore, the existed deeper part of CO2 in the wellbore is easier to diffuse to the top area.

As shown in Figures and , the surface microbial activity is enhanced as the atmospheric temperature increases. Due to the influence of air leakage from the open-pit slope to the goaf, the surface CO2 flux increases. From the changes in CO2 concentration in the borehole, it can be found that with increasing temperature, a large fluctuation in the CO2 concentration was measured near the surface of the borehole (within a depth of 1 m) due to the increase in CO2 emission. It is important to point out that the atmospheric temperature and slope leakage affect the goaf CO2 diffusion and promote the emission of CO2 on the surface. Note that the concentration of CO2 in the H ≥ 3 m area becomes smaller. Meanwhile, the CO2 concentration in the borehole is influenced not only by the goaf but also the diffusion of the surrounding stratum.

Figure 14

Surface CO2 flux curve.

The above preliminary analysis has provided important information that there is a certain amount of CO2 in the upper stratum and the CO2 diffusion from the goaf to the surface.

Surface Soil CO2 Fluxes Related to Spontaneous Combustion in the Goaf

The coal mines have (#3 point location area) already closed the mine shafts, roadways around goafs 2 years ago. There is a smoking belt fissured from the north to the south on the surface. Therefore, air leakage from the slope surface provides oxygen to residual coal in the goaf and may induce spontaneous combustion in the goaf.

As shown in Figure , the value of CO2 flux at the #3 point overlying the goaf is roughly 10 times larger than that of the #2 point on the normal soil surface due to spontaneous combustion of the residual coal. We expect that the main environmental and topographic factors to induce spontaneous combustion at the goaf are atmospheric temperature, wind velocity, and wind direction at the pit slope surface.

Figure 15

Relationship between the CO2 flux and temperature at the #3 point.

According to the environmental monitoring data at the site, the influence of wind velocity on the surface CO2 flux over the goaf is discussed, because the wind direction of the monitoring area is mainly west wind. Figure shows the relation between the wind velocity and surface soil CO2 flux. The trend of CO2 flux is sensitive to the wind velocity. The reason may be that the goaf air leakage induces with increasing wind velocity, and it promotes the coal oxidation and producing CO2 gas. This phenomenon is attributed to the increase in the surface CO2 flux.

Figure 16

Relationship between the CO2 flux and wind velocity at the #3 point.

Figures and 18 show the relationships between the goaf surface soil CO2 flux, temperature, and wind velocity for V ≤ 2 m·s–1 and V > 2 m·s–1, respectively. Under the influence of the air leakage from the slope and the temperature difference between the goaf and the outside, the wind speed and the atmospheric temperature dominate the fluctuation of the surface CO2 flux. When the wind speed is less than 2 m·s–1, the temperature plays a leading role. When the wind speed is higher than 2 m·s–1, the wind speed dominates the fluctuation of the CO2 flux. Accordingly, the correlation between the surface soil CO2 flux and the temperature on V > 2 m·s–1 is more sensitive to the wind velocity than that of V ≤ 2 m·s–1.

Figure 17

Relationship among the surface CO2 flux, temperature, and wind velocity at the #3 point (V ≤ 2 m·s–1): (a) surface CO2 flux versus temperature and (b) surface CO2 flux versus wind velocity.

Figure 18

Relationship among the CO2 flux, temperature, and wind velocity at the #3 point (V > 2 m·s–1): (a) surface CO2 flux versus temperature and (b) surface CO2 flux versus wind velocity.

Conclusions

In this study, the CO2 concentration in the borehole connected to the goaf and CO2 flux in the soil surface was carried out to investigate the influence of abandoned coal mine goaf CO2 on the surface environment. The present study is summarized as follows:

The surface CO2 flux over the goaf is obviously higher than that of the normal area. The measured CO2 flux over the goaf is mainly provided from the oxidation reaction of residual coal. The present measurement results are useful for early warning to prevent hazards related to spontaneous combustion in the goaf or shallow coal seams.

Both surface CO2 fluxes over the goaf and the normal area are affected by the soil characteristics and atmospheric temperature. However, the CO2 flux in the normal area increases with increasing atmospheric temperature, while the CO2 flux over the goaf decreases with increasing atmospheric temperature.

The CO2 concentration in the borehole is basically constant when the depth is higher than 1 m. The difference in the concentration at different depths indicates the presence of CO2 diffusion in the stratum.

The tracer gas method proved the air leakage in the goaf. The air leakage intensity is proportional to the magnitude of wind velocity. It was found that the fracture in the area of the #3 point is connected to the goaf. The air leakage from the open-pit slope was expected to promote the surface CO2 emission over the goaf.